Molecular-ink route to 13.0% efficient low-bandgap CuIn(S,Se) sub(2) and 14.7% efficient Cu(In,Ga)(S,Se) sub(2) solar cells

A stable dimethyl sulfoxide (DMSO)-based ink containing a copper-thiourea-chloride complex and an indium-DMSO-chloride complex leads to 13.0% efficient CuIn(S,Se) sub(2) (CIS) solar cells, which is a record for solution processed CIS. The formation of these complexes was found critical to control ox...

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Veröffentlicht in:	Energy & environmental science 2016-01, Vol.9 (1), p.130-134
Hauptverfasser:	Uhl, A R, Katahara, J K, Hillhouse, H W
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Sprache:	eng
Schlagworte:	Dimethyl sulfoxide Formations INKS Photovoltaic cells Solar cells VALENCE
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description	A stable dimethyl sulfoxide (DMSO)-based ink containing a copper-thiourea-chloride complex and an indium-DMSO-chloride complex leads to 13.0% efficient CuIn(S,Se) sub(2) (CIS) solar cells, which is a record for solution processed CIS. The formation of these complexes was found critical to control oxidation states and loss of metals during processing and to tailor the final composition of the absorber.
doi_str_mv	10.1039/c5ee02870a
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Dimethyl sulfoxide Formations INKS Photovoltaic cells Solar cells VALENCE
title	Molecular-ink route to 13.0% efficient low-bandgap CuIn(S,Se) sub(2) and 14.7% efficient Cu(In,Ga)(S,Se) sub(2) solar cells
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