Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation

Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation

We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction involves the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox conditions. We report a synthesis method for the construc...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (28), p.4987-499
Hauptverfasser: Fearnley, A. F, An, J, Jackson, M, Lindovska, P, Denton, R. M
Format: Artikel
Sprache:eng
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Ambient temperature
Aromatic compounds
Construction
Coupling
Phosphines
Radicals
Synthesis
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container_end_page 499
container_issue 28
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container_title Chemical communications (Cambridge, England)
container_volume 52
creator Fearnley, A. F
An, J
Jackson, M
Lindovska, P
Denton, R. M
description We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction involves the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox conditions. We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature.
doi_str_mv 10.1039/c6cc00556j
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source Alma/SFX Local Collection; Royal Society of Chemistry E-Journals
subjects Ambient temperature
Aromatic compounds
Construction
Coupling
Phosphines
Radicals
Synthesis
title Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation
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