Single crystal to single crystal [2+2] photoreactions in chloride and sulphate salts of 4-amino-cinnamic acid via solid-solution formation: a structural and kinetic study
A set of molecular salts with general formula [1H]nA·xH2O (1 = 4-amino-cinnamic acid, A(n-) = NO3(-), BF4(-), PF6(-), SO4(2-), x = 0, 1) was prepared and structurally characterized. [1H]Cl and [1H]2SO4·H2O(II) were found to undergo an SCSC stepwise [2+2] photodimerization, which was followed by X-ra...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (9), p.1899-1902 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 52 |
| creator | d'Agostino, Simone Spinelli, Floriana Boanini, Elisa Braga, Dario Grepioni, Fabrizia |
| description | A set of molecular salts with general formula [1H]nA·xH2O (1 = 4-amino-cinnamic acid, A(n-) = NO3(-), BF4(-), PF6(-), SO4(2-), x = 0, 1) was prepared and structurally characterized. [1H]Cl and [1H]2SO4·H2O(II) were found to undergo an SCSC stepwise [2+2] photodimerization, which was followed by X-ray diffraction; a kinetic analysis was performed on single crystals of both salts. In the case of [1H]Cl the photoreaction was also studied on polycrystalline materials. |
| doi_str_mv | 10.1039/c5cc09412g |
| format | Article |
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[1H]Cl and [1H]2SO4·H2O(II) were found to undergo an SCSC stepwise [2+2] photodimerization, which was followed by X-ray diffraction; a kinetic analysis was performed on single crystals of both salts. 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[1H]Cl and [1H]2SO4·H2O(II) were found to undergo an SCSC stepwise [2+2] photodimerization, which was followed by X-ray diffraction; a kinetic analysis was performed on single crystals of both salts. 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[1H]Cl and [1H]2SO4·H2O(II) were found to undergo an SCSC stepwise [2+2] photodimerization, which was followed by X-ray diffraction; a kinetic analysis was performed on single crystals of both salts. In the case of [1H]Cl the photoreaction was also studied on polycrystalline materials.</abstract><cop>England</cop><pmid>26673406</pmid><doi>10.1039/c5cc09412g</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Chlorides Diffraction Formations Single crystals Sulfates X-rays |
| title | Single crystal to single crystal [2+2] photoreactions in chloride and sulphate salts of 4-amino-cinnamic acid via solid-solution formation: a structural and kinetic study |
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