Lifetime estimation applying a kinetic model based on the generalized logistic function to biopolymers
The aim of this work was to estimate the lifetime due thermal aging of polymers and even other materials using a new approach based on the application of a kinetic model based on the generalized logistic function. For this purpose, thermogravimetric analysis, including dynamic and isothermal tests,...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2015-12, Vol.122 (3), p.1203-1212 |
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| container_end_page | 1212 |
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| container_title | Journal of thermal analysis and calorimetry |
| container_volume | 122 |
| creator | Tarrío-Saavedra, Javier López-Beceiro, Jorge Álvarez, Ana Naya, Salvador Quintana-Pita, Sara García-Pardo, Santiago García-Sabán, Francisco Javier |
| description | The aim of this work was to estimate the lifetime due thermal aging of polymers and even other materials using a new approach based on the application of a kinetic model based on the generalized logistic function. For this purpose, thermogravimetric analysis, including dynamic and isothermal tests, was performed for different formulations based on polylactic acid used in dental applications (scaffolds). In this work, lifetime is defined as the time passed for losing the 5 wt% of the mass corresponding to the first and main degradation process. The 5 mass% mass loss could be a critic parameter in manufacturing processes, in terms of economical profit and quality of the final product. The proposed model provides lifetime estimates of polymeric materials depending on the storage temperature. The present procedure permits to obtain lifetime estimates of materials characterized by more than one main degradation process, since they can be dis-overlapped using generalized logistic functions. |
| doi_str_mv | 10.1007/s10973-015-5083-1 |
| format | Article |
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The present procedure permits to obtain lifetime estimates of materials characterized by more than one main degradation process, since they can be dis-overlapped using generalized logistic functions.</description><subject>Analysis</subject><subject>Analytical Chemistry</subject><subject>Biopolymers</subject><subject>Calorimetry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Degradation</subject><subject>Dental materials</subject><subject>Estimates</subject><subject>Inorganic Chemistry</subject><subject>Logistics</subject><subject>Mathematical models</subject><subject>Measurement Science and Instrumentation</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Product life cycle</subject><subject>Service life assessment</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kctu1TAQhiMEEqXwAOy8hEVaX46deFlVUCodqRKXtWU7k-Di2MFOJA5PzxzCphvkxYzG3z9jz980bxm9YpR215VR3YmWMtlK2ouWPWsumOz7lmuunmMuMFdM0pfNq1ofKaVaU3bRjMcwwhpmIFAx2DXkROyyxFNIE7HkR0h47cmcB4jE2QoDQWL9DmSCBMXG8BtLMU-hnrlxS_5vjzUTF_KS42mGUl83L0YbK7z5Fy-bbx8_fL391B4f7u5vb46tF_qwtn6QzHHOFHNaD12vHAA-k4LFKMFzK7gS1GnXea88uF5LOYJ3vWBcKiUum3d736Xknxt-ycyheojRJshbNaynPVUH0XFEr3Z0shFMSGNei_V4BpiDzwnGgPWbg5CUS5yDgvdPBMis8Gud7Faruf_y-SnLdtaXXGuB0SwFt1tOhlFzNszshhk0zJwNMww1fNdUZNMExTzmrSRc139EfwDlSJk_</recordid><startdate>20151201</startdate><enddate>20151201</enddate><creator>Tarrío-Saavedra, Javier</creator><creator>López-Beceiro, Jorge</creator><creator>Álvarez, Ana</creator><creator>Naya, Salvador</creator><creator>Quintana-Pita, Sara</creator><creator>García-Pardo, Santiago</creator><creator>García-Sabán, Francisco Javier</creator><general>Springer Netherlands</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20151201</creationdate><title>Lifetime estimation applying a kinetic model based on the generalized logistic function to biopolymers</title><author>Tarrío-Saavedra, Javier ; 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| subjects | Analysis Analytical Chemistry Biopolymers Calorimetry Chemistry Chemistry and Materials Science Degradation Dental materials Estimates Inorganic Chemistry Logistics Mathematical models Measurement Science and Instrumentation Physical Chemistry Polymer Sciences Product life cycle Service life assessment |
| title | Lifetime estimation applying a kinetic model based on the generalized logistic function to biopolymers |
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