Synthesis, crystal structure, optical and thermal properties of lanthanide hydrogen-polyphosphates Ln[H(PO3)4] (Ln = Tb, Dy, Ho)

Lanthanide hydrogen-polyphosphates Ln[H(PO3)4] (Ln = Tb, Dy, Ho) were synthesised as colourless (Ln = Tb, Dy) and light pink (Ln = Ho) crystalline powders by reaction of Tb4O7/Dy2O3/Ho2O3 with H3PO3 at 380 °C. All compounds crystallise isotypically (P2(1)/c (no. 14), Z = 4, a(Tb) = 1368.24(4) pm, b(...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2015-11, Vol.44 (44), p.19163-19174
Hauptverfasser:	g, Katharina, Hoppe, Henning A
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystal structure Dysprosium Helical Lanthanides Optical properties Polyphosphates Spectra Thermal properties
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!