Direct Synthesis of Phospholyl Lithium from White Phosphorus

The selective construction of P−C bonds directly from P4 and nucleophiles is an ideal and step‐economical approach to utilizing elemental P4 for the straightforward synthesis of organophosphorus compounds. In this work, a highly efficient one‐pot reaction between P4 and 1,4‐dilithio‐1,3‐butadienes w...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-08, Vol.55 (32), p.9187-9190
Hauptverfasser:	Xu, Ling, Chi, Yue, Du, Shanshan, Zhang, Wen-Xiong, Xi, Zhenfeng
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Bonding Chemical synthesis Cleavage Construction C−P coupling Lithium Nucleophiles Organophosphorus compounds P4 functionalization phospholyl lithium Phosphorus Selectivity synthetic methods
Online-Zugang:	Volltext
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