The organochlorine contamination history of the Mersey estuary, UK, revealed by analysis of sediment cores from salt marshes

Sediment profiles in the Banks, Ince and Widnes Warth salt marshes in Northwest England contain a mappable record of historic pollution. For persistent organochlorine compounds this stretches back over 90 years. The PCB and HCH profiles can be successfully rationalised by dating methods, and they ca...

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Veröffentlicht in:Marine environmental research 2001-04, Vol.51 (3), p.213-227
Hauptverfasser: Fox, W.M, Connor, L, Copplestone, D, Johnson, M.S, Leah, R.T
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container_title Marine environmental research
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creator Fox, W.M
Connor, L
Copplestone, D
Johnson, M.S
Leah, R.T
description Sediment profiles in the Banks, Ince and Widnes Warth salt marshes in Northwest England contain a mappable record of historic pollution. For persistent organochlorine compounds this stretches back over 90 years. The PCB and HCH profiles can be successfully rationalised by dating methods, and they can be related to the dates of initial production and subsequent withdrawal from use of these chemicals as a result of restrictive environmental legislation. HCB has a more complex pollution profile as it has been manufactured in Northwest England, both deliberately as a pesticide and accidentally as a by-product of several chlorination processes, dating back to the start of the 20th century. The concentrations of degradation products of DDT are relatively constant through the sediment profile and are dominated by op′- and pp′-DDD with only minor contributions from the most toxic species, pp′-DDT. The quantities of these compounds resident in the reservoir of pollutants under these marshes have been calculated, and have fallen progressively in the last 30–50 years.
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subjects Applied sciences
Brackish
British Isles, England, Mersey Estuary
DDT
Earth sciences
Earth, ocean, space
Engineering and environment geology. Geothermics
England
Environmental Monitoring
Environmental Pollutants - analysis
Exact sciences and technology
Geologic Sediments - chemistry
HCB
HCH
Industry
Insecticides - analysis
Lindane - analysis
Mersey estuary
Natural water pollution
PCB
Pollution
Pollution sources. Measurement results
Pollution, environment geology
Polychlorinated Biphenyls - analysis
Salt marshes
Seawaters, estuaries
Sediment cores
Soil and sediments pollution
Water Pollutants, Chemical - analysis
Water treatment and pollution
title The organochlorine contamination history of the Mersey estuary, UK, revealed by analysis of sediment cores from salt marshes
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