N-Substituted Dicyanomethylphenyl Radicals: Dynamic Covalent Properties and Formation of Stimuli-Responsive Cyclophanes by Self-Assembly

Dynamic covalent bonds and their chemistry have been of particular interest both from a fundamental and materials science aspect. Demonstrated herein is that triphenylamine (TPA) and carbazole (Cz), substituted with a dicyanomethyl radical, are useful motifs for dynamic covalent chemistry as they ha...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-07, Vol.55 (30), p.8634-8638
Hauptverfasser:	Kobashi, Toshiyuki, Sakamaki, Daisuke, Seki, Shu
Format:	Artikel
Sprache:	eng
Schlagworte:	Bond strength cyclophanes radicals self-assembly substituent effects thermochromism
Online-Zugang:	Volltext
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