An efficient method for the synthesis of pyranoid glycals

A simple and efficient procedure was designed for the preparation of pyranoid glycals. In a novel fashion, a series of protected glycopyranosyl bromides underwent reductive elimination in the presence of zinc dust and ammonium chloride in CH3CN at 30–60 °C. The corresponding glycals were obtained wi...

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Veröffentlicht in:	Carbohydrate research 2016-08, Vol.431, p.42-46
Hauptverfasser:	Chen, Heshan, Xian, Ting, Zhang, Wan, Si, Wenshuai, Luo, Xiaosheng, Zhang, Bo, Zhang, Meiyu, Wang, Zhongfu, Zhang, Jianbo
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Ammonium chloride Ammonium Chloride - chemistry Bromides - chemistry Glycals Glycopyranosyl bromides Glycosides - chemical synthesis Glycosides - chemistry Molecular Structure Zinc Zinc - chemistry
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