First Cationic Uranyl–Organic Framework with Anion-Exchange Capabilities

First Cationic Uranyl–Organic Framework with Anion-Exchange Capabilities

By controlling the extent of hydrolysis during the self-assembly process of a zwitterionic-based ligand with uranyl cations, we observed a structural evolution from the neutral uranyl–organic framework [(UO2)2(TTTPC)­(OH)­O­(COOH)]·1.5DMF·7H2O (SCU-6) to the first cationic uranyl–organic framework w...

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Veröffentlicht in:Inorganic chemistry 2016-07, Vol.55 (13), p.6358-6360
Hauptverfasser: Bai, Zhuanling, Wang, Yanlong, Li, Yuxiang, Liu, Wei, Chen, Lanhua, Sheng, Daopeng, Diwu, Juan, Chai, Zhifang, Albrecht-Schmitt, Thomas E, Wang, Shuao
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container_end_page 6360
container_issue 13
container_start_page 6358
container_title Inorganic chemistry
container_volume 55
creator Bai, Zhuanling
Wang, Yanlong
Li, Yuxiang
Liu, Wei
Chen, Lanhua
Sheng, Daopeng
Diwu, Juan
Chai, Zhifang
Albrecht-Schmitt, Thomas E
Wang, Shuao
description By controlling the extent of hydrolysis during the self-assembly process of a zwitterionic-based ligand with uranyl cations, we observed a structural evolution from the neutral uranyl–organic framework [(UO2)2(TTTPC)­(OH)­O­(COOH)]·1.5DMF·7H2O (SCU-6) to the first cationic uranyl–organic framework with the formula of [(UO2)­(HTTTPC)­(OH)]­Br·1.5DMF·4H2O (SCU-7). The crystal structures of SCU-6 and SCU-7 are layers built with tetranuclear and dinuclear uranyl clusters, respectively. Exchangeable halide anions are present in the interlaminar spaces balancing the positive charge of layers in SCU-7. Therefore, SCU-7 is able to effectively remove perrhenate anions from aqueous solution. Meanwhile, the H2PO4 –-exchanged SCU-7 material exhibits a moderate proton conductivity of 8.70 × 10–5 S cm–1 at 50 °C and 90% relative humidity, representing nearly 80 times enhancement compared to the original material.
doi_str_mv 10.1021/acs.inorgchem.6b00930
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title First Cationic Uranyl–Organic Framework with Anion-Exchange Capabilities
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