Troponate/Aminotroponate Ruthenium–Arene Complexes: Synthesis, Structure, and Ligand-Tuned Mechanistic Pathway for Direct C–H Bond Arylation with Aryl Chlorides in Water

A series of water-soluble troponate/aminotroponate ruthenium­(II)–arene complexes were synthesized, where O,O and N,O chelating troponate/aminotroponate ligands stabilized the piano-stool mononuclear ruthenium–arene complexes. Structural identities for two of the representating complexes were also e...

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Veröffentlicht in:Inorganic chemistry 2016-07, Vol.55 (13), p.6739-6749
Hauptverfasser: Dwivedi, Ambikesh D, Binnani, Chinky, Tyagi, Deepika, Rawat, Kuber S, Li, Pei-Zhou, Zhao, Yanli, Mobin, Shaikh M, Pathak, Biswarup, Singh, Sanjay K
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Sprache:eng
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