Low-temperature concentration of tellurium and gold in continental red bed successions
There is very little understanding of tellurium (Te) distribution and behaviour in sedimentary rocks. A suite of 15 samples of reduction spheroids (centimetre‐scale pale spheroids in otherwise red rock), including samples from eight localities in Triassic red beds across the British Isles, were mapp...
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description | There is very little understanding of tellurium (Te) distribution and behaviour in sedimentary rocks. A suite of 15 samples of reduction spheroids (centimetre‐scale pale spheroids in otherwise red rock), including samples from eight localities in Triassic red beds across the British Isles, were mapped for Te using Laser Ablation–Inductively Coupled Plasma–Mass Spectrometry. Almost all showed enrichment in Te in the cores of the spheroids relative to background red bed concentrations, by up to four orders of magnitude. Some were also enriched over background in gold and/or mercury. In one case, discrete telluride minerals were recorded. The data show that Te is mobile and can be concentrated in low‐temperature sedimentary environments, controlled by redox variations. The consistency in enrichment across widely separate localities implies that the enrichment is a normal aspect of red bed diagenesis and so likely to be controlled by a ubiquitous process, such as microbial activity. |
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A suite of 15 samples of reduction spheroids (centimetre‐scale pale spheroids in otherwise red rock), including samples from eight localities in Triassic red beds across the British Isles, were mapped for Te using Laser Ablation–Inductively Coupled Plasma–Mass Spectrometry. Almost all showed enrichment in Te in the cores of the spheroids relative to background red bed concentrations, by up to four orders of magnitude. Some were also enriched over background in gold and/or mercury. In one case, discrete telluride minerals were recorded. The data show that Te is mobile and can be concentrated in low‐temperature sedimentary environments, controlled by redox variations. The consistency in enrichment across widely separate localities implies that the enrichment is a normal aspect of red bed diagenesis and so likely to be controlled by a ubiquitous process, such as microbial activity.</description><identifier>ISSN: 0954-4879</identifier><identifier>EISSN: 1365-3121</identifier><identifier>DOI: 10.1111/ter.12213</identifier><language>eng</language><publisher>Oxford: Blackwell Publishing Ltd</publisher><subject>Diagenesis ; Gold ; Low temperature ; Mass spectrometry ; Mercury ; Microbial activity ; Plasma ; Sedimentary environments ; Sedimentary geology ; Sedimentary rocks ; Tellurium ; Temperature ; Triassic</subject><ispartof>Terra nova (Oxford, England), 2016-06, Vol.28 (3), p.221-227</ispartof><rights>2016 The Authors. 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A suite of 15 samples of reduction spheroids (centimetre‐scale pale spheroids in otherwise red rock), including samples from eight localities in Triassic red beds across the British Isles, were mapped for Te using Laser Ablation–Inductively Coupled Plasma–Mass Spectrometry. Almost all showed enrichment in Te in the cores of the spheroids relative to background red bed concentrations, by up to four orders of magnitude. Some were also enriched over background in gold and/or mercury. In one case, discrete telluride minerals were recorded. The data show that Te is mobile and can be concentrated in low‐temperature sedimentary environments, controlled by redox variations. The consistency in enrichment across widely separate localities implies that the enrichment is a normal aspect of red bed diagenesis and so likely to be controlled by a ubiquitous process, such as microbial activity.</description><subject>Diagenesis</subject><subject>Gold</subject><subject>Low temperature</subject><subject>Mass spectrometry</subject><subject>Mercury</subject><subject>Microbial activity</subject><subject>Plasma</subject><subject>Sedimentary environments</subject><subject>Sedimentary geology</subject><subject>Sedimentary rocks</subject><subject>Tellurium</subject><subject>Temperature</subject><subject>Triassic</subject><issn>0954-4879</issn><issn>1365-3121</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNp10E9LwzAYBvAgCs7pwW9Q8KKHzrxJ_6RHN-YmjAky5zGkSSqdbTOTlrlvb2bVg2AghMDvCW8ehC4Bj8Cv21bbERAC9AgNgCZxSIHAMRrgLI7CiKXZKTpzboMxTlOSDdB6YXZhq-uttqLtrA6kaaRuWn8rTROYImh1VXW27OpANCp4NZUKyubA2rLxUFSB1SrI_XadlNo5n3Pn6KQQldMX3-cQPd9PV5N5uHicPUzuFqGISEJDJggRRFKZJCzBitA4SjWIJIpzSnIaMw1As5hKpYjKKRUsUiKKGMhCxUmS0iG67t_dWvPeadfyunTSTywabTrHgWFCMMGUeHr1h25MZxs_HYeUpRgyAObVTa-kNc5ZXfCtLWth9xwwPzTMfcP8q2Fvb3u7Kyu9_x_y1fTpJxH2idK1-uM3Iewb959JY_6ynPH5erweZ5Mln9FPleyLgg</recordid><startdate>201606</startdate><enddate>201606</enddate><creator>Parnell, John</creator><creator>Spinks, Samuel</creator><creator>Bellis, David</creator><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>24P</scope><scope>WIN</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>F1W</scope><scope>H96</scope><scope>L.G</scope><scope>7UA</scope><scope>C1K</scope></search><sort><creationdate>201606</creationdate><title>Low-temperature concentration of tellurium and gold in continental red bed successions</title><author>Parnell, John ; Spinks, Samuel ; Bellis, David</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a4263-8a22a2c3c66860d23547e1a645b32b358e113953cdd2db33a84da4481cfd56673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Diagenesis</topic><topic>Gold</topic><topic>Low temperature</topic><topic>Mass spectrometry</topic><topic>Mercury</topic><topic>Microbial activity</topic><topic>Plasma</topic><topic>Sedimentary environments</topic><topic>Sedimentary geology</topic><topic>Sedimentary rocks</topic><topic>Tellurium</topic><topic>Temperature</topic><topic>Triassic</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Parnell, John</creatorcontrib><creatorcontrib>Spinks, Samuel</creatorcontrib><creatorcontrib>Bellis, David</creatorcontrib><collection>Istex</collection><collection>Wiley Online Library Open Access</collection><collection>Wiley Online Library Free Content</collection><collection>CrossRef</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><jtitle>Terra nova (Oxford, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Parnell, John</au><au>Spinks, Samuel</au><au>Bellis, David</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Low-temperature concentration of tellurium and gold in continental red bed successions</atitle><jtitle>Terra nova (Oxford, England)</jtitle><addtitle>Terra Nova</addtitle><date>2016-06</date><risdate>2016</risdate><volume>28</volume><issue>3</issue><spage>221</spage><epage>227</epage><pages>221-227</pages><issn>0954-4879</issn><eissn>1365-3121</eissn><abstract>There is very little understanding of tellurium (Te) distribution and behaviour in sedimentary rocks. A suite of 15 samples of reduction spheroids (centimetre‐scale pale spheroids in otherwise red rock), including samples from eight localities in Triassic red beds across the British Isles, were mapped for Te using Laser Ablation–Inductively Coupled Plasma–Mass Spectrometry. Almost all showed enrichment in Te in the cores of the spheroids relative to background red bed concentrations, by up to four orders of magnitude. Some were also enriched over background in gold and/or mercury. In one case, discrete telluride minerals were recorded. The data show that Te is mobile and can be concentrated in low‐temperature sedimentary environments, controlled by redox variations. The consistency in enrichment across widely separate localities implies that the enrichment is a normal aspect of red bed diagenesis and so likely to be controlled by a ubiquitous process, such as microbial activity.</abstract><cop>Oxford</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/ter.12213</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Diagenesis Gold Low temperature Mass spectrometry Mercury Microbial activity Plasma Sedimentary environments Sedimentary geology Sedimentary rocks Tellurium Temperature Triassic |
title | Low-temperature concentration of tellurium and gold in continental red bed successions |
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