Review on the Reactivity of 1,1-Diamino-2,2-dinitroethylene (FOX-7)
1,1‐Diamino‐2,2‐dinitroethylene (FOX‐7) is a novel high‐energy insensitive material with good thermal stability and low sensitivity, and exhibits excellent application performance in the field of insensitive ammunitions and solid propellant. Although FOX‐7 is simple in molecular composition and stru...
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| Veröffentlicht in: | Propellants, explosives, pyrotechnics explosives, pyrotechnics, 2016-02, Vol.41 (1), p.35-52 |
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| container_title | Propellants, explosives, pyrotechnics |
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| creator | Zhang, Yu Sun, Qian Xu, Kangzhen Song, Jirong Zhao, Fengqi |
| description | 1,1‐Diamino‐2,2‐dinitroethylene (FOX‐7) is a novel high‐energy insensitive material with good thermal stability and low sensitivity, and exhibits excellent application performance in the field of insensitive ammunitions and solid propellant. Although FOX‐7 is simple in molecular composition and structure, its chemical reactivity is abundant and surprising, including salification reaction, coordination reaction, nucleophilic substitution reaction, acetylate reaction, oxidizing reaction, reduction reaction, electrophilic addition reaction, among other reactions. These reactions are systemically summarized and some reaction mechanisms are analyzed in this review. |
| doi_str_mv | 10.1002/prep.201500065 |
| format | Article |
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Although FOX‐7 is simple in molecular composition and structure, its chemical reactivity is abundant and surprising, including salification reaction, coordination reaction, nucleophilic substitution reaction, acetylate reaction, oxidizing reaction, reduction reaction, electrophilic addition reaction, among other reactions. 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These reactions are systemically summarized and some reaction mechanisms are analyzed in this review.</description><subject>1,1‐Diamino‐2,2‐dinitroethylene (FOX‐7)</subject><subject>1-Diamino-2</subject><subject>2-dinitroethylene (FOX-7)</subject><subject>Ammunition</subject><subject>Chemical reactions</subject><subject>Energetic materials</subject><subject>Explosives</subject><subject>Insensitive ammunition</subject><subject>Molecular structure</subject><subject>Nitro enamine</subject><subject>Propellants</subject><subject>Pyrotechnics</subject><subject>Reaction mechanisms</subject><subject>Solid propellants</subject><issn>0721-3115</issn><issn>1521-4087</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkE1Lw0AQQBdRsH5cPQe8VOjW2c8kR22tClKlKnpbtsmUbk2TuJuq_fdGKiJePM0c3huGR8gRgz4D4Ke1x7rPgSkA0GqLdJjijEpI4m3SgbjdBWNql-yFsABoFWAdMpjgm8P3qCqjZo7RBG3WuDfXrKNqFrEeo0Nnl66sKO9xmrvSNb7CZr4usMSoO7p9pvHJAdmZ2SLg4ffcJ4-ji4fBFb25vbwenN3QTKpE0SwXOYc8kylX0xS5Ap6A5DqZSmFTlSsx1ZJbMWPW5lxnQqRaoxYJBwu5QLFPupu7ta9eVxgas3Qhw6KwJVarYFgCIFPNuWzR4z_oolr5sv3OsFhLzVOWJC3V31CZr0LwODO1d0vr14aB-Wpqvpqan6atkG6Ed1fg-h_a3E0u7n67dOO60ODHj2v9i9GxiJV5Gl-a4fnDZDS-ujdCfAKdIIXw</recordid><startdate>201602</startdate><enddate>201602</enddate><creator>Zhang, Yu</creator><creator>Sun, Qian</creator><creator>Xu, Kangzhen</creator><creator>Song, Jirong</creator><creator>Zhao, Fengqi</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>201602</creationdate><title>Review on the Reactivity of 1,1-Diamino-2,2-dinitroethylene (FOX-7)</title><author>Zhang, Yu ; Sun, Qian ; Xu, Kangzhen ; Song, Jirong ; Zhao, Fengqi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4585-cd3d20dc4925b9e2502804268b43a95d53b642a3f1aad26c33966e63820a0d3e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>1,1‐Diamino‐2,2‐dinitroethylene (FOX‐7)</topic><topic>1-Diamino-2</topic><topic>2-dinitroethylene (FOX-7)</topic><topic>Ammunition</topic><topic>Chemical reactions</topic><topic>Energetic materials</topic><topic>Explosives</topic><topic>Insensitive ammunition</topic><topic>Molecular structure</topic><topic>Nitro enamine</topic><topic>Propellants</topic><topic>Pyrotechnics</topic><topic>Reaction mechanisms</topic><topic>Solid propellants</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yu</creatorcontrib><creatorcontrib>Sun, Qian</creatorcontrib><creatorcontrib>Xu, Kangzhen</creatorcontrib><creatorcontrib>Song, Jirong</creatorcontrib><creatorcontrib>Zhao, Fengqi</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Propellants, explosives, pyrotechnics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yu</au><au>Sun, Qian</au><au>Xu, Kangzhen</au><au>Song, Jirong</au><au>Zhao, Fengqi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Review on the Reactivity of 1,1-Diamino-2,2-dinitroethylene (FOX-7)</atitle><jtitle>Propellants, explosives, pyrotechnics</jtitle><addtitle>Propellants, Explosives, Pyrotechnics</addtitle><date>2016-02</date><risdate>2016</risdate><volume>41</volume><issue>1</issue><spage>35</spage><epage>52</epage><pages>35-52</pages><issn>0721-3115</issn><eissn>1521-4087</eissn><abstract>1,1‐Diamino‐2,2‐dinitroethylene (FOX‐7) is a novel high‐energy insensitive material with good thermal stability and low sensitivity, and exhibits excellent application performance in the field of insensitive ammunitions and solid propellant. Although FOX‐7 is simple in molecular composition and structure, its chemical reactivity is abundant and surprising, including salification reaction, coordination reaction, nucleophilic substitution reaction, acetylate reaction, oxidizing reaction, reduction reaction, electrophilic addition reaction, among other reactions. These reactions are systemically summarized and some reaction mechanisms are analyzed in this review.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/prep.201500065</doi><tpages>18</tpages></addata></record> |
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| identifier | ISSN: 0721-3115 |
| ispartof | Propellants, explosives, pyrotechnics, 2016-02, Vol.41 (1), p.35-52 |
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| source | Access via Wiley Online Library |
| subjects | 1,1‐Diamino‐2,2‐dinitroethylene (FOX‐7) 1-Diamino-2 2-dinitroethylene (FOX-7) Ammunition Chemical reactions Energetic materials Explosives Insensitive ammunition Molecular structure Nitro enamine Propellants Pyrotechnics Reaction mechanisms Solid propellants |
| title | Review on the Reactivity of 1,1-Diamino-2,2-dinitroethylene (FOX-7) |
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