Unusual Thermal Decomposition of Ag super(II)SO sub(4) Yielding Ag super(I) sub(2)S sub(2 )O sub(7): Bending Hammond's Rule

O sub(2) at low expense from Ag super(II)SO sub(4): Silver(II) sulfate provides the first example among metal sulfates of low-temperature "reductive" thermal decomposition, which results in Ag super(I) disulfate and molecular dioxygen. Despite the similarity of this reaction to the one kno...

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Veröffentlicht in:	Chemistry : a European journal 2011-09, Vol.17 (38), p.10524-10527
Hauptverfasser:	Malinowski, Przemyslaw Jan, Derzsi, Mariana, Budzianowski, Armand, Leszczyski, Piotr J, Gawe, Bartlomiej, Mazej, Zoran, Grochala, Wojciech
Format:	Artikel
Sprache:	eng
Schlagworte:	Bending Expenses Reaction kinetics Similarity Sulfates Thermal decomposition Thermodynamics
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description	O sub(2) at low expense from Ag super(II)SO sub(4): Silver(II) sulfate provides the first example among metal sulfates of low-temperature "reductive" thermal decomposition, which results in Ag super(I) disulfate and molecular dioxygen. Despite the similarity of this reaction to the one known for peroxodisulfates (e.g., K sub(2)S sub(2)O sub(8)), the thermodynamics and kinetics of both processes are markedly different, and when compared they severely disobey Hammond's rule (see scheme).
doi_str_mv	10.1002/chem.201101952
format	Article
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subjects	Bending Expenses Reaction kinetics Similarity Sulfates Thermal decomposition Thermodynamics
title	Unusual Thermal Decomposition of Ag super(II)SO sub(4) Yielding Ag super(I) sub(2)S sub(2 )O sub(7): Bending Hammond's Rule
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