Development of a Potentiometric Chemical Sensor for the Rapid Detection of Carbofuran Based on Air Stable Lipid Films with Incorporated Calix[4]arene Phosphoryl Receptor Using Graphene Electrodes
The present article describes a miniaturized potentiometric carbofuran chemical sensor on graphene nanosheets with incorporated lipid films. The graphene electrode was used for the development of a very selective and sensitive chemical sensor for the detection of carbofuran by immobilizing an artifi...
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| Veröffentlicht in: | Electroanalysis (New York, N.Y.) N.Y.), 2015-11, Vol.27 (11), p.2608-2613 |
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| container_title | Electroanalysis (New York, N.Y.) |
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| creator | Bratakou, Spyridoula Nikoleli, Georgia-Paraskevi Nikolelis, Dimitrios P. Psaroudakis, Nikolas |
| description | The present article describes a miniaturized potentiometric carbofuran chemical sensor on graphene nanosheets with incorporated lipid films. The graphene electrode was used for the development of a very selective and sensitive chemical sensor for the detection of carbofuran by immobilizing an artificial selective receptor on stabilized lipid films. The artificial receptor was synthesized by transformation of the hydroxyl groups of resorcin[4]arene receptor into phosphoryl groups. This chemical sensor responded for the wide range of carbofuran concentrations with fast response time of ca. 20 s. The presented potentiometric carbofuran chemical sensor is easy to construct and exhibits good reproducibility, reusability, selectivity, rapid response times, long shelf life and high sensitivity of ca. 59 mV/decade over the carbofuran logarithmic concentration range from 10−6 to 10−3 M. |
| doi_str_mv | 10.1002/elan.201500299 |
| format | Article |
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| identifier | ISSN: 1040-0397 |
| ispartof | Electroanalysis (New York, N.Y.), 2015-11, Vol.27 (11), p.2608-2613 |
| issn | 1040-0397 1521-4109 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Calixarene phosphoryl receptor Carbofuran chemical sensor Chemical sensors Electrodes Graphene Graphene nanosheets Lipids Potentiometric chemical sensors Receptors Reproducibility Response time Stabilized lipid films Transformations |
| title | Development of a Potentiometric Chemical Sensor for the Rapid Detection of Carbofuran Based on Air Stable Lipid Films with Incorporated Calix[4]arene Phosphoryl Receptor Using Graphene Electrodes |
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