Phenalenyl-Based Organozinc Catalysts for Intramolecular Hydroamination Reactions: A Combined Catalytic, Kinetic, and Mechanistic Investigation of the Catalytic Cycle

Herein, we report the synthesis and characterization of two organozinc complexes that contain symmetrical phenalenyl (PLY)‐based N,N‐ligands. The reactions of phenalenyl‐based ligands with ZnMe2 led to the formation of organozinc complexes [N(Me),N(Me)‐PLY]ZnMe (1) and [N(iPr),N(iPr)‐PLY]ZnMe (2) un...

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