Rapid fabrication of poly(ε-caprolactone) nanofibers using needleless alternating current electrospinning
ABSTRACT Poly(ε‐caprolactone) (PCL) biopolymer nanofibers and micro‐fibers have been fabricated for the first time at the rates up to 14.0 g per hour using a needleless and collectorless alternating current electrospinning technique. By combining the ac‐voltage, “green” low toxicity glacial acetic a...
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| Veröffentlicht in: | Journal of applied polymer science 2016-04, Vol.133 (13), p.np-n/a |
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| container_title | Journal of applied polymer science |
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| creator | Lawson, Caitlin Stanishevsky, Andrei Sivan, Manikandan Pokorny, Pavel Lukáš, David |
| description | ABSTRACT
Poly(ε‐caprolactone) (PCL) biopolymer nanofibers and micro‐fibers have been fabricated for the first time at the rates up to 14.0 g per hour using a needleless and collectorless alternating current electrospinning technique. By combining the ac‐voltage, “green” low toxicity glacial acetic acid (AA) as the solvent and sodium acetate (NaAc) as an additive, beadless PCL fibers with diameters tunable from 150 nm to 2000 nm, varying surface morphology and degree of self‐bundling are obtained. In this new approach, the addition of NaAc plays a crucial role in improving the spinnability of PCL solution and fiber morphology. NaAc reveals the concentration‐dependent effect on charge transfer and rheological properties of the PCL/AA precursor, which results in broader ranges of spinnable PCL concentrations and ac‐voltages suitable for rapid manufacturing of PCL‐based fibers. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43232. |
| doi_str_mv | 10.1002/app.43232 |
| format | Article |
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Poly(ε‐caprolactone) (PCL) biopolymer nanofibers and micro‐fibers have been fabricated for the first time at the rates up to 14.0 g per hour using a needleless and collectorless alternating current electrospinning technique. By combining the ac‐voltage, “green” low toxicity glacial acetic acid (AA) as the solvent and sodium acetate (NaAc) as an additive, beadless PCL fibers with diameters tunable from 150 nm to 2000 nm, varying surface morphology and degree of self‐bundling are obtained. In this new approach, the addition of NaAc plays a crucial role in improving the spinnability of PCL solution and fiber morphology. NaAc reveals the concentration‐dependent effect on charge transfer and rheological properties of the PCL/AA precursor, which results in broader ranges of spinnable PCL concentrations and ac‐voltages suitable for rapid manufacturing of PCL‐based fibers. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43232.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.43232</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Blackwell Publishing Ltd</publisher><subject>Alternating current ; biodegradable ; Electrospinning ; Fibers ; Materials science ; Morphology ; Nanofibers ; polyesters ; Polymers ; Precursors ; Rapid manufacturing ; Toxicity ; viscosity and viscoelasticity</subject><ispartof>Journal of applied polymer science, 2016-04, Vol.133 (13), p.np-n/a</ispartof><rights>2015 Wiley Periodicals, Inc.</rights><rights>2016 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5102-fff04143bf6259e4a8855b5fc2cd2880e674df36c1d007773101952119a7f1ff3</citedby><cites>FETCH-LOGICAL-c5102-fff04143bf6259e4a8855b5fc2cd2880e674df36c1d007773101952119a7f1ff3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.43232$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.43232$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,27911,27912,45561,45562</link.rule.ids></links><search><creatorcontrib>Lawson, Caitlin</creatorcontrib><creatorcontrib>Stanishevsky, Andrei</creatorcontrib><creatorcontrib>Sivan, Manikandan</creatorcontrib><creatorcontrib>Pokorny, Pavel</creatorcontrib><creatorcontrib>Lukáš, David</creatorcontrib><title>Rapid fabrication of poly(ε-caprolactone) nanofibers using needleless alternating current electrospinning</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
Poly(ε‐caprolactone) (PCL) biopolymer nanofibers and micro‐fibers have been fabricated for the first time at the rates up to 14.0 g per hour using a needleless and collectorless alternating current electrospinning technique. By combining the ac‐voltage, “green” low toxicity glacial acetic acid (AA) as the solvent and sodium acetate (NaAc) as an additive, beadless PCL fibers with diameters tunable from 150 nm to 2000 nm, varying surface morphology and degree of self‐bundling are obtained. In this new approach, the addition of NaAc plays a crucial role in improving the spinnability of PCL solution and fiber morphology. NaAc reveals the concentration‐dependent effect on charge transfer and rheological properties of the PCL/AA precursor, which results in broader ranges of spinnable PCL concentrations and ac‐voltages suitable for rapid manufacturing of PCL‐based fibers. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43232.</description><subject>Alternating current</subject><subject>biodegradable</subject><subject>Electrospinning</subject><subject>Fibers</subject><subject>Materials science</subject><subject>Morphology</subject><subject>Nanofibers</subject><subject>polyesters</subject><subject>Polymers</subject><subject>Precursors</subject><subject>Rapid manufacturing</subject><subject>Toxicity</subject><subject>viscosity and viscoelasticity</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kEFuFDEQRS0EEkNgwQ1aYpMsOinb7bZ7GSIIkARGCITExvK4y8iDY3fsbsEcjGtwJkwGWERiVVL997-qPiFPKRxTAHZipum444yze2RFYZBt1zN1n6yqRls1DOIheVTKFoBSAf2KbN-byY-NM5vsrZl9ik1yzZTC7vDnj9aaKadg7JwiHjXRxOT8BnNpluLjlyYijgEDltKYMGOONaCu7ZIzxrmpip1zKpOPse4fkwfOhIJP_swD8vHliw9nr9rLd-evz04vWysosNY5Bx3t-Mb1TAzYGaWE2AhnmR2ZUoC97EbHe0tHACklp0AHwSgdjHTUOX5ADve59fabBcusr32xGIKJmJaiqQLolBo6VdFnd9BtWuoboVJSSJA9B16poz1l6zMlo9NT9tcm7zQF_bt1XVvXt61X9mTPfvMBd_8H9el6_dfR7h2-zPj9n8Pkr7qXXAr96e25_rx-85xeXCkt-S-s7pQq</recordid><startdate>20160405</startdate><enddate>20160405</enddate><creator>Lawson, Caitlin</creator><creator>Stanishevsky, Andrei</creator><creator>Sivan, Manikandan</creator><creator>Pokorny, Pavel</creator><creator>Lukáš, David</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160405</creationdate><title>Rapid fabrication of poly(ε-caprolactone) nanofibers using needleless alternating current electrospinning</title><author>Lawson, Caitlin ; Stanishevsky, Andrei ; Sivan, Manikandan ; Pokorny, Pavel ; Lukáš, David</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5102-fff04143bf6259e4a8855b5fc2cd2880e674df36c1d007773101952119a7f1ff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Alternating current</topic><topic>biodegradable</topic><topic>Electrospinning</topic><topic>Fibers</topic><topic>Materials science</topic><topic>Morphology</topic><topic>Nanofibers</topic><topic>polyesters</topic><topic>Polymers</topic><topic>Precursors</topic><topic>Rapid manufacturing</topic><topic>Toxicity</topic><topic>viscosity and viscoelasticity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lawson, Caitlin</creatorcontrib><creatorcontrib>Stanishevsky, Andrei</creatorcontrib><creatorcontrib>Sivan, Manikandan</creatorcontrib><creatorcontrib>Pokorny, Pavel</creatorcontrib><creatorcontrib>Lukáš, David</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lawson, Caitlin</au><au>Stanishevsky, Andrei</au><au>Sivan, Manikandan</au><au>Pokorny, Pavel</au><au>Lukáš, David</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rapid fabrication of poly(ε-caprolactone) nanofibers using needleless alternating current electrospinning</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2016-04-05</date><risdate>2016</risdate><volume>133</volume><issue>13</issue><spage>np</spage><epage>n/a</epage><pages>np-n/a</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
Poly(ε‐caprolactone) (PCL) biopolymer nanofibers and micro‐fibers have been fabricated for the first time at the rates up to 14.0 g per hour using a needleless and collectorless alternating current electrospinning technique. By combining the ac‐voltage, “green” low toxicity glacial acetic acid (AA) as the solvent and sodium acetate (NaAc) as an additive, beadless PCL fibers with diameters tunable from 150 nm to 2000 nm, varying surface morphology and degree of self‐bundling are obtained. In this new approach, the addition of NaAc plays a crucial role in improving the spinnability of PCL solution and fiber morphology. NaAc reveals the concentration‐dependent effect on charge transfer and rheological properties of the PCL/AA precursor, which results in broader ranges of spinnable PCL concentrations and ac‐voltages suitable for rapid manufacturing of PCL‐based fibers. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43232.</abstract><cop>Hoboken</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.43232</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Alternating current biodegradable Electrospinning Fibers Materials science Morphology Nanofibers polyesters Polymers Precursors Rapid manufacturing Toxicity viscosity and viscoelasticity |
| title | Rapid fabrication of poly(ε-caprolactone) nanofibers using needleless alternating current electrospinning |
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