Photocatalyst-Free and Blue Light-Induced RAFT Polymerization of Vinyl Acetate at Ambient Temperature

Vinyl acetate is polymerized in the living way under the irradiation of blue light‐emitting diodes (LEDs) or sunlight without photocatalyst at ambient temperature. 2‐(Ethoxycarbonothioyl)sulfanyl propanoate is exclusively added and acts as initiator and chain transfer agent simultaneously in the cur...

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Veröffentlicht in:	Macromolecular rapid communications. 2015-12, Vol.36 (24), p.2181-2185
Hauptverfasser:	Ding, Chunlai, Fan, Caiwei, Jiang, Ganquan, Pan, Xiangqiang, Zhang, Zhengbiao, Zhu, Jian, Zhu, Xiulin
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates Acetic acid Addition polymerization Ambient temperature Chain transfer Desorption Ionization Ions Irradiation Light Light emitting diodes living radical polymerization Mass spectrometry Mass spectroscopy Molecular weight Molecular weight distribution NMR Nuclear magnetic resonance Photocatalysts Photochemical Processes photoinitiated polymerization poly(vinyl acetate) polymer chemistry Polymerization Polymers Polyvinyls - analysis Polyvinyls - chemical synthesis Polyvinyls - chemistry Radicals Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization - methods Vinyl acetate
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