Surface effects on thermoelectric properties of metallic and semiconducting nanowires

Metallic and semiconducting nanowires (NWs) are of interest in the field of thermoelectrics, because they act as model system to investigate the influence of surfaces on the thermoelectric transport properties. In single crystalline NWs, the grain boundary scattering is negligible and the surface‐to...

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Veröffentlicht in:Physica status solidi. A, Applications and materials science Applications and materials science, 2016-03, Vol.213 (3), p.557-570
Hauptverfasser: Kojda, Danny, Mitdank, Rüdiger, Weidemann, Stefan, Mogilatenko, Anna, Wang, Zhi, Ruhhammer, Johannes, Kroener, Michael, Töllner, William, Woias, Peter, Nielsch, Kornelius, Fischer, Saskia F.
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container_title Physica status solidi. A, Applications and materials science
container_volume 213
creator Kojda, Danny
Mitdank, Rüdiger
Weidemann, Stefan
Mogilatenko, Anna
Wang, Zhi
Ruhhammer, Johannes
Kroener, Michael
Töllner, William
Woias, Peter
Nielsch, Kornelius
Fischer, Saskia F.
description Metallic and semiconducting nanowires (NWs) are of interest in the field of thermoelectrics, because they act as model system to investigate the influence of surfaces on the thermoelectric transport properties. In single crystalline NWs, the grain boundary scattering is negligible and the surface‐to‐volume‐ratio is high. We present state‐of‐the‐art of the combination of the structural, chemical, and temperature‐dependent full thermoelectric characterization for individual single crystalline NWs, which is essential to conclude on surface effects. Temperature‐dependent measurements allow further conclusions on the scattering mechanisms. Simulations by the finite element method are performed on indented NWs to interpret the measurement results. Calculated surface temperature of a single‐indented and a multi‐indented NW. Combined thermoelectrical, structural and chemical characterisation of individual metallic and semiconducting nanowires is presented. In the temperature range between 4.2 K and room temperature the thermoelectrical properties are determined. Transmission electron microscopy yields the structural properties, the chemical composition and the morphology of the nanowires. This comprehensive study unambiguously allows identifying surface effects on the thermoelectric properties and scattering mechanisms for electrons and phonons.
doi_str_mv 10.1002/pssa.201532464
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subjects Computer simulation
Crystal structure
Finite element analysis
finite element method
Grain boundaries
Lorenz number
Materials science
Nanowires
Scattering
surface effects
Surface temperature
Thermoelectricity
Thermoelectrics
title Surface effects on thermoelectric properties of metallic and semiconducting nanowires
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