Carboranylphosphinic Acids: A New Class of Purely Inorganic Ligands
Purely inorganic carboranyl phosphinates were prepared, and the influence of the cluster on the reactivity of the phosphinate group was studied. Electron‐withdrawal by the carboranyl carbon atoms, combined with space‐filling efficiency and enhanced aromaticity of the cluster cage, renders the phosph...
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| Veröffentlicht in: | Chemistry : a European journal 2016-03, Vol.22 (11), p.3665-3670 |
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| creator | Oleshkevich, Elena Teixidor, Francesc Choquesillo-Lazarte, Duane Sillanpää, Reijo Viñas, Clara |
| description | Purely inorganic carboranyl phosphinates were prepared, and the influence of the cluster on the reactivity of the phosphinate group was studied. Electron‐withdrawal by the carboranyl carbon atoms, combined with space‐filling efficiency and enhanced aromaticity of the cluster cage, renders the phosphorus more difficult to oxidize. This enables carboranyl phosphinates to survive harsh oxidizing conditions, a property which is uncommon in organic phosphinates.
Purely inorganic carboranyl phosphinates were prepared and the influence of the cluster on the reactivity of the phosphinate group was studied (see figure). Electron‐withdrawal by the carboranyl carbon atoms, combined with space‐filling efficiency and enhanced aromaticity of the cluster cage, renders the phosphorus more difficult to oxidize. This enables carboranyl phosphinates to survive harsh oxidizing conditions. |
| doi_str_mv | 10.1002/chem.201504408 |
| format | Article |
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Purely inorganic carboranyl phosphinates were prepared and the influence of the cluster on the reactivity of the phosphinate group was studied (see figure). Electron‐withdrawal by the carboranyl carbon atoms, combined with space‐filling efficiency and enhanced aromaticity of the cluster cage, renders the phosphorus more difficult to oxidize. This enables carboranyl phosphinates to survive harsh oxidizing conditions.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201504408</identifier><identifier>PMID: 26638876</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>Acids ; Aromaticity ; Cage ; Carbon ; carboranes ; Chemistry ; Clusters ; hydrogen bonding ; hydrophobicity ; Ligands ; Oxidation ; phosphinates ; phosphonates ; Phosphorus</subject><ispartof>Chemistry : a European journal, 2016-03, Vol.22 (11), p.3665-3670</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5518-484bbbfd00a4249815327b8c17b02d4561d84f6b1806940c3d5b913782f77d1b3</citedby><cites>FETCH-LOGICAL-c5518-484bbbfd00a4249815327b8c17b02d4561d84f6b1806940c3d5b913782f77d1b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201504408$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201504408$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26638876$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Oleshkevich, Elena</creatorcontrib><creatorcontrib>Teixidor, Francesc</creatorcontrib><creatorcontrib>Choquesillo-Lazarte, Duane</creatorcontrib><creatorcontrib>Sillanpää, Reijo</creatorcontrib><creatorcontrib>Viñas, Clara</creatorcontrib><title>Carboranylphosphinic Acids: A New Class of Purely Inorganic Ligands</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>Purely inorganic carboranyl phosphinates were prepared, and the influence of the cluster on the reactivity of the phosphinate group was studied. Electron‐withdrawal by the carboranyl carbon atoms, combined with space‐filling efficiency and enhanced aromaticity of the cluster cage, renders the phosphorus more difficult to oxidize. This enables carboranyl phosphinates to survive harsh oxidizing conditions, a property which is uncommon in organic phosphinates.
Purely inorganic carboranyl phosphinates were prepared and the influence of the cluster on the reactivity of the phosphinate group was studied (see figure). Electron‐withdrawal by the carboranyl carbon atoms, combined with space‐filling efficiency and enhanced aromaticity of the cluster cage, renders the phosphorus more difficult to oxidize. This enables carboranyl phosphinates to survive harsh oxidizing conditions.</description><subject>Acids</subject><subject>Aromaticity</subject><subject>Cage</subject><subject>Carbon</subject><subject>carboranes</subject><subject>Chemistry</subject><subject>Clusters</subject><subject>hydrogen bonding</subject><subject>hydrophobicity</subject><subject>Ligands</subject><subject>Oxidation</subject><subject>phosphinates</subject><subject>phosphonates</subject><subject>Phosphorus</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkT1v2zAYhImiQe06XTsWArpkkfPym8rmCI5jwHU7JKg3gpSoWoksOWQE1_8-NJwYRZdMtzx3wN0h9BXDGAOQy2LtNmMCmANjoD6gIeYEp1QK_hENIWMyFZxmA_Q5hAcAyASln9CACEGVkmKI8tx423nT7pvtugvbdd3WRTIp6jJcJZNk6XZJ3pgQkq5KfvXeNftk3nb-jzlgizpqGc7RWWWa4L686gjd30zv8tt08XM2zyeLtOAcq5QpZq2tSgDDCMsU5pRIqwosLZCScYFLxSphsQKRMShoyW2GqVSkkrLElo7QxTF367un3oVnvalD4ZrGtK7rg45GYIpSId9HpQSCJcQdRuj7f-hD1_s2FomUyCgWTPJIjY9U4bsQvKv01tcb4_cagz48oQ9P6NMT0fDtNba3G1ee8LfpI5AdgV3duP07cTq_nf74Nzw9euvw7P6evMY_6lhecv17OdM3szs5w6trvaIvJ_6gig</recordid><startdate>20160307</startdate><enddate>20160307</enddate><creator>Oleshkevich, Elena</creator><creator>Teixidor, Francesc</creator><creator>Choquesillo-Lazarte, Duane</creator><creator>Sillanpää, Reijo</creator><creator>Viñas, Clara</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20160307</creationdate><title>Carboranylphosphinic Acids: A New Class of Purely Inorganic Ligands</title><author>Oleshkevich, Elena ; Teixidor, Francesc ; Choquesillo-Lazarte, Duane ; Sillanpää, Reijo ; Viñas, Clara</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5518-484bbbfd00a4249815327b8c17b02d4561d84f6b1806940c3d5b913782f77d1b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Acids</topic><topic>Aromaticity</topic><topic>Cage</topic><topic>Carbon</topic><topic>carboranes</topic><topic>Chemistry</topic><topic>Clusters</topic><topic>hydrogen bonding</topic><topic>hydrophobicity</topic><topic>Ligands</topic><topic>Oxidation</topic><topic>phosphinates</topic><topic>phosphonates</topic><topic>Phosphorus</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oleshkevich, Elena</creatorcontrib><creatorcontrib>Teixidor, Francesc</creatorcontrib><creatorcontrib>Choquesillo-Lazarte, Duane</creatorcontrib><creatorcontrib>Sillanpää, Reijo</creatorcontrib><creatorcontrib>Viñas, Clara</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oleshkevich, Elena</au><au>Teixidor, Francesc</au><au>Choquesillo-Lazarte, Duane</au><au>Sillanpää, Reijo</au><au>Viñas, Clara</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carboranylphosphinic Acids: A New Class of Purely Inorganic Ligands</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2016-03-07</date><risdate>2016</risdate><volume>22</volume><issue>11</issue><spage>3665</spage><epage>3670</epage><pages>3665-3670</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>Purely inorganic carboranyl phosphinates were prepared, and the influence of the cluster on the reactivity of the phosphinate group was studied. Electron‐withdrawal by the carboranyl carbon atoms, combined with space‐filling efficiency and enhanced aromaticity of the cluster cage, renders the phosphorus more difficult to oxidize. This enables carboranyl phosphinates to survive harsh oxidizing conditions, a property which is uncommon in organic phosphinates.
Purely inorganic carboranyl phosphinates were prepared and the influence of the cluster on the reactivity of the phosphinate group was studied (see figure). Electron‐withdrawal by the carboranyl carbon atoms, combined with space‐filling efficiency and enhanced aromaticity of the cluster cage, renders the phosphorus more difficult to oxidize. This enables carboranyl phosphinates to survive harsh oxidizing conditions.</abstract><cop>Germany</cop><pub>Blackwell Publishing Ltd</pub><pmid>26638876</pmid><doi>10.1002/chem.201504408</doi><tpages>6</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Acids Aromaticity Cage Carbon carboranes Chemistry Clusters hydrogen bonding hydrophobicity Ligands Oxidation phosphinates phosphonates Phosphorus |
| title | Carboranylphosphinic Acids: A New Class of Purely Inorganic Ligands |
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