Bio-Based Polyketones by Selective Ring-Opening Radical Polymerization of α-Pinene-Derived Pinocarvone

The most abundant naturally occurring terpene, α‐pinene, which cannot be directly polymerized into high polymers by any polymerization method, was quantitatively converted under visible‐light irradiation into pinocarvone, which possesses a reactive exo methylene group. The bicyclic vinyl ketone was...

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Veröffentlicht in:	Angewandte Chemie 2016-01, Vol.128 (4), p.1394-1398
Hauptverfasser:	Miyaji, Hisanari, Satoh, Kotaro, Kamigaito, Masami
Format:	Artikel
Sprache:	eng
Schlagworte:	Addition polymerization Blockcopolymere Erneuerbare Ressourcen Ketones Methylene Polymerization Radicals Radikalische Polymerisation Rafts Reagents Ringöffnungspolymerisation Terpenoide Thermal properties
Online-Zugang:	Volltext
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