Electronic Structure Evaluation of an Oxidized Tris(methoxy)-Substituted Ni Salen Complex

The Ni salen complex N,N′‐bis(2,3,4‐trimethoxysalicylidene)‐1,2‐cyclohexane‐(1R,2R)‐diamine nickel(II) (1), containing ortho‐, meta‐, and para‐methoxy‐substituted phenolate moieties, was prepared. Electrochemical studies revealed that the first oxidation of 1 occurs at a similar potential to a previ...

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Veröffentlicht in:	European journal of inorganic chemistry 2016-01, Vol.2016 (1), p.49-55
Hauptverfasser:	Chiang, Linus, Clarke, Ryan M., Herasymchuk, Khrystyna, Sutherland, Mathew, Prosser, Kathleen E., Shimazaki, Yuichi, Storr, Tim
Format:	Artikel
Sprache:	eng
Schlagworte:	Bands Density functional calculations Electronic structure Ligand design Ligands Localization N,O ligands Nickel O ligands Oxidation Position (location) Radicals Redox chemistry
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