Novel comb polymers from alternating N-acylated poly(aminoester)s obtained by spontaneous zwitterionic copolymerisation
N-Acylated poly(aminoester) (NPAE) macromonomers were synthesised via spontaneous copolymerisation of 2-oxazolines and acrylic acid. Inherent quantitative introduction of α-vinyl end-groups was observed, which enabled the preparation of a series of well-defined NPAE comb polymers through redox-initi...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (90), p.16213-16216 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Kempe, Kristian de Jongh, Patrick A J M Anastasaki, Athina Wilson, Paul Haddleton, David M |
| description | N-Acylated poly(aminoester) (NPAE) macromonomers were synthesised via spontaneous copolymerisation of 2-oxazolines and acrylic acid. Inherent quantitative introduction of α-vinyl end-groups was observed, which enabled the preparation of a series of well-defined NPAE comb polymers through redox-initiated RAFT polymerisation. Investigations of the thermal properties of the comb polymers revealed similarities to poly(2-oxazoline) based systems. |
| doi_str_mv | 10.1039/c5cc07247f |
| format | Article |
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| ispartof | Chemical communications (Cambridge, England), 2015-01, Vol.51 (90), p.16213-16216 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Acrylates - chemistry Acrylic acid Acylation Analogies Copolymerization Esters Molecular Structure Oxazoles - chemistry Polyamines - chemical synthesis Polyamines - chemistry Polymerization Rafts Spontaneous Thermal properties |
| title | Novel comb polymers from alternating N-acylated poly(aminoester)s obtained by spontaneous zwitterionic copolymerisation |
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