Fe(III) recovery from HCl solutions using amberlite XAD-7 resin impregnated with a tetraalkyl phosphonium ionic liquid
Fe(III) is efficiently extracted from concentrated HCl solutions using Amberlite XAD‐7 impregnated with tetraalkyl phosphonium chloride ionic liquid (IL) (synthesis of extractant‐impregnated resin, EIR). The sorption efficiency is controlled by metal speciation and IL loading in the EIR. Sorption is...
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| Veröffentlicht in: | Canadian journal of chemical engineering 2016-01, Vol.94 (1), p.107-116 |
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| container_title | Canadian journal of chemical engineering |
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| creator | Navarro, Ricardo Saucedo, Imelda Gallardo, Violeta Guibal, Eric |
| description | Fe(III) is efficiently extracted from concentrated HCl solutions using Amberlite XAD‐7 impregnated with tetraalkyl phosphonium chloride ionic liquid (IL) (synthesis of extractant‐impregnated resin, EIR). The sorption efficiency is controlled by metal speciation and IL loading in the EIR. Sorption isotherms in mono‐component solutions are described by the Langmuir equation, while the extended Langmuir equation perfectly fits sorption isotherms from binary Fe(III)/Zn(II) solutions. The thermodynamic study confirms the endothermic nature of the sorption. Uptake kinetics are fitted by the pseudo‐second order rate equation. While temperature and metal concentration have a relatively limited effect on kinetics, the IL content more significantly affects the mass transfer of Fe(III). Water, sodium sulphate, nitric acid, and sulphuric acid almost completely desorb Fe(III) from loaded EIRs. Resin recycling was tested for eight cycles without significant decrease of the sorption and desorption efficiencies. |
| doi_str_mv | 10.1002/cjce.22356 |
| format | Article |
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The sorption efficiency is controlled by metal speciation and IL loading in the EIR. Sorption isotherms in mono‐component solutions are described by the Langmuir equation, while the extended Langmuir equation perfectly fits sorption isotherms from binary Fe(III)/Zn(II) solutions. The thermodynamic study confirms the endothermic nature of the sorption. Uptake kinetics are fitted by the pseudo‐second order rate equation. While temperature and metal concentration have a relatively limited effect on kinetics, the IL content more significantly affects the mass transfer of Fe(III). Water, sodium sulphate, nitric acid, and sulphuric acid almost completely desorb Fe(III) from loaded EIRs. Resin recycling was tested for eight cycles without significant decrease of the sorption and desorption efficiencies.</description><identifier>ISSN: 0008-4034</identifier><identifier>EISSN: 1939-019X</identifier><identifier>DOI: 10.1002/cjce.22356</identifier><language>eng</language><publisher>Blackwell Publishing Ltd</publisher><subject>Amberlite (trademark) ; Chlorides ; Engineering Sciences ; Fe(III) ; Ionic liquids ; Isotherms ; kinetics ; Mathematical analysis ; Polymers ; resin recycling ; Resins ; Sorption ; sorption isotherms ; tetraalkyl phosphonium ionic liquid</subject><ispartof>Canadian journal of chemical engineering, 2016-01, Vol.94 (1), p.107-116</ispartof><rights>2015 Canadian Society for Chemical Engineering</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5216-7aabb62c0570e11e40d8713f4210bb01cb4cd55569ddec65bc9be6b37fbffe6e3</citedby><cites>FETCH-LOGICAL-c5216-7aabb62c0570e11e40d8713f4210bb01cb4cd55569ddec65bc9be6b37fbffe6e3</cites><orcidid>0000-0002-2767-6305</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcjce.22356$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcjce.22356$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1416,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02906418$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Navarro, Ricardo</creatorcontrib><creatorcontrib>Saucedo, Imelda</creatorcontrib><creatorcontrib>Gallardo, Violeta</creatorcontrib><creatorcontrib>Guibal, Eric</creatorcontrib><title>Fe(III) recovery from HCl solutions using amberlite XAD-7 resin impregnated with a tetraalkyl phosphonium ionic liquid</title><title>Canadian journal of chemical engineering</title><addtitle>Can. J. Chem. Eng.</addtitle><description>Fe(III) is efficiently extracted from concentrated HCl solutions using Amberlite XAD‐7 impregnated with tetraalkyl phosphonium chloride ionic liquid (IL) (synthesis of extractant‐impregnated resin, EIR). The sorption efficiency is controlled by metal speciation and IL loading in the EIR. Sorption isotherms in mono‐component solutions are described by the Langmuir equation, while the extended Langmuir equation perfectly fits sorption isotherms from binary Fe(III)/Zn(II) solutions. The thermodynamic study confirms the endothermic nature of the sorption. Uptake kinetics are fitted by the pseudo‐second order rate equation. While temperature and metal concentration have a relatively limited effect on kinetics, the IL content more significantly affects the mass transfer of Fe(III). Water, sodium sulphate, nitric acid, and sulphuric acid almost completely desorb Fe(III) from loaded EIRs. Resin recycling was tested for eight cycles without significant decrease of the sorption and desorption efficiencies.</description><subject>Amberlite (trademark)</subject><subject>Chlorides</subject><subject>Engineering Sciences</subject><subject>Fe(III)</subject><subject>Ionic liquids</subject><subject>Isotherms</subject><subject>kinetics</subject><subject>Mathematical analysis</subject><subject>Polymers</subject><subject>resin recycling</subject><subject>Resins</subject><subject>Sorption</subject><subject>sorption isotherms</subject><subject>tetraalkyl phosphonium ionic liquid</subject><issn>0008-4034</issn><issn>1939-019X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kcFu1DAQhi0EEkvhwhP42CKljJ3ETo6r0Ha3XYEQIHqzbGfSdeskWzvZsm9PlkCPHEajGX3ff_kJec_gnAHwj_be4jnnaS5ekAUr0zIBVt6-JAsAKJIM0uw1eRPj_XRyyNiC7C_xdL1en9GAtt9jONAm9C1dVZ7G3o-D67tIx-i6O6pbg8G7Aent8lMiJ2N6U9fuAt51esCaPrlhSzUdcAha-4eDp7ttH6fp3NjSKcpZ6t3j6Oq35FWjfcR3f_cJ-XF58b1aJZsvV-tquUlszplIpNbGCG4hl4CMYQZ1IVnaZJyBMcCsyWyd57ko6xqtyI0tDQqTysY0DQpMT8jZnLvVXu2Ca3U4qF47tVpu1PEHvASRsWLPJvZ0ZnehfxwxDqp10aL3usN-jIoVAFkBkssJ_TCjNvQxBmyesxmoYxHqWIT6U8QEsxl-ch4P_yFVdV1d_HOS2XFxwF_Pjg4PSshU5urn5yv17eb6poCNUF_T3ziYmrY</recordid><startdate>201601</startdate><enddate>201601</enddate><creator>Navarro, Ricardo</creator><creator>Saucedo, Imelda</creator><creator>Gallardo, Violeta</creator><creator>Guibal, Eric</creator><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-2767-6305</orcidid></search><sort><creationdate>201601</creationdate><title>Fe(III) recovery from HCl solutions using amberlite XAD-7 resin impregnated with a tetraalkyl phosphonium ionic liquid</title><author>Navarro, Ricardo ; Saucedo, Imelda ; Gallardo, Violeta ; Guibal, Eric</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5216-7aabb62c0570e11e40d8713f4210bb01cb4cd55569ddec65bc9be6b37fbffe6e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Amberlite (trademark)</topic><topic>Chlorides</topic><topic>Engineering Sciences</topic><topic>Fe(III)</topic><topic>Ionic liquids</topic><topic>Isotherms</topic><topic>kinetics</topic><topic>Mathematical analysis</topic><topic>Polymers</topic><topic>resin recycling</topic><topic>Resins</topic><topic>Sorption</topic><topic>sorption isotherms</topic><topic>tetraalkyl phosphonium ionic liquid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Navarro, Ricardo</creatorcontrib><creatorcontrib>Saucedo, Imelda</creatorcontrib><creatorcontrib>Gallardo, Violeta</creatorcontrib><creatorcontrib>Guibal, Eric</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Canadian journal of chemical engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Navarro, Ricardo</au><au>Saucedo, Imelda</au><au>Gallardo, Violeta</au><au>Guibal, Eric</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fe(III) recovery from HCl solutions using amberlite XAD-7 resin impregnated with a tetraalkyl phosphonium ionic liquid</atitle><jtitle>Canadian journal of chemical engineering</jtitle><addtitle>Can. J. Chem. Eng.</addtitle><date>2016-01</date><risdate>2016</risdate><volume>94</volume><issue>1</issue><spage>107</spage><epage>116</epage><pages>107-116</pages><issn>0008-4034</issn><eissn>1939-019X</eissn><abstract>Fe(III) is efficiently extracted from concentrated HCl solutions using Amberlite XAD‐7 impregnated with tetraalkyl phosphonium chloride ionic liquid (IL) (synthesis of extractant‐impregnated resin, EIR). The sorption efficiency is controlled by metal speciation and IL loading in the EIR. Sorption isotherms in mono‐component solutions are described by the Langmuir equation, while the extended Langmuir equation perfectly fits sorption isotherms from binary Fe(III)/Zn(II) solutions. The thermodynamic study confirms the endothermic nature of the sorption. Uptake kinetics are fitted by the pseudo‐second order rate equation. While temperature and metal concentration have a relatively limited effect on kinetics, the IL content more significantly affects the mass transfer of Fe(III). Water, sodium sulphate, nitric acid, and sulphuric acid almost completely desorb Fe(III) from loaded EIRs. Resin recycling was tested for eight cycles without significant decrease of the sorption and desorption efficiencies.</abstract><pub>Blackwell Publishing Ltd</pub><doi>10.1002/cjce.22356</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-2767-6305</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Amberlite (trademark) Chlorides Engineering Sciences Fe(III) Ionic liquids Isotherms kinetics Mathematical analysis Polymers resin recycling Resins Sorption sorption isotherms tetraalkyl phosphonium ionic liquid |
| title | Fe(III) recovery from HCl solutions using amberlite XAD-7 resin impregnated with a tetraalkyl phosphonium ionic liquid |
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