New tetraphosphite ligands for regioselective linear hydroformylation of terminal and internal olefins
We successfully developed new tetraphosphite ligands L1–L5 and applied them to the rhodium-catalyzed hydroformylation of terminal and internal olefins. High catalytic reactivities and excellent regioselectivities for linear aldehydes were obtained in the rhodium-catalyzed hydroformylation of simple...
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| Veröffentlicht in: | RSC advances 2016-01, Vol.6 (18), p.14559-14562 |
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| container_title | RSC advances |
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| creator | Zhang, Zongpeng Chen, Caiyou Wang, Qian Han, Zhengyu Dong, Xiu-Qin Zhang, Xumu |
| description | We successfully developed new tetraphosphite ligands
L1–L5
and applied them to the rhodium-catalyzed hydroformylation of terminal and internal olefins. High catalytic reactivities and excellent regioselectivities for linear aldehydes were obtained in the rhodium-catalyzed hydroformylation of simple olefins (l/b ratio up to 90, 98.9% linear selectivity, 99.2% conversion) using the tetraphosphite ligand
L2
. And the tetraphosphite ligand
L2
also displayed moderate to good linear regioselectivities for challenging substrates styrene and internal olefin 2-octene. |
| doi_str_mv | 10.1039/C5RA23683E |
| format | Article |
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L1–L5
and applied them to the rhodium-catalyzed hydroformylation of terminal and internal olefins. High catalytic reactivities and excellent regioselectivities for linear aldehydes were obtained in the rhodium-catalyzed hydroformylation of simple olefins (l/b ratio up to 90, 98.9% linear selectivity, 99.2% conversion) using the tetraphosphite ligand
L2
. And the tetraphosphite ligand
L2
also displayed moderate to good linear regioselectivities for challenging substrates styrene and internal olefin 2-octene.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/C5RA23683E</identifier><language>eng</language><subject>Catalysis ; Conversion ; Ligands ; Olefins ; Rhodium ; Selectivity ; Styrenes ; Terminals</subject><ispartof>RSC advances, 2016-01, Vol.6 (18), p.14559-14562</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c330t-7f44a93999d23019fcd83d7302e07c150cee2909ec64d41e07e446d6da958c663</citedby><cites>FETCH-LOGICAL-c330t-7f44a93999d23019fcd83d7302e07c150cee2909ec64d41e07e446d6da958c663</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhang, Zongpeng</creatorcontrib><creatorcontrib>Chen, Caiyou</creatorcontrib><creatorcontrib>Wang, Qian</creatorcontrib><creatorcontrib>Han, Zhengyu</creatorcontrib><creatorcontrib>Dong, Xiu-Qin</creatorcontrib><creatorcontrib>Zhang, Xumu</creatorcontrib><title>New tetraphosphite ligands for regioselective linear hydroformylation of terminal and internal olefins</title><title>RSC advances</title><description>We successfully developed new tetraphosphite ligands
L1–L5
and applied them to the rhodium-catalyzed hydroformylation of terminal and internal olefins. High catalytic reactivities and excellent regioselectivities for linear aldehydes were obtained in the rhodium-catalyzed hydroformylation of simple olefins (l/b ratio up to 90, 98.9% linear selectivity, 99.2% conversion) using the tetraphosphite ligand
L2
. And the tetraphosphite ligand
L2
also displayed moderate to good linear regioselectivities for challenging substrates styrene and internal olefin 2-octene.</description><subject>Catalysis</subject><subject>Conversion</subject><subject>Ligands</subject><subject>Olefins</subject><subject>Rhodium</subject><subject>Selectivity</subject><subject>Styrenes</subject><subject>Terminals</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNUE1LAzEQDaJgqb34C3IUYTXZZLObYynVCkVB9LyEZNJGsps1SZX-e3epoHOZefM-Dg-ha0ruKGHyflW9LksmGrY-Q7OScFGURMjzf_clWqT0QcYRFS0FnSH7DN84Q45q2Ic07F0G7N1O9SZhGyKOsHMhgQed3ddE9aAi3h9NDCPdHb3KLvQ42DEkdq5XHo9e7PoRTiB4sK5PV-jCKp9g8bvn6P1h_bbaFNuXx6fVcltoxkguasu5kkxKaUpGqLTaNMzUjJRAak0rogFKSSRowQ2n4xM4F0YYJatGC8Hm6OaUO8TweYCU284lDd6rHsIhtbQhhNdS8kl6e5LqGFKKYNshuk7FY0tJO_XZ_vXJfgDN4mlN</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Zhang, Zongpeng</creator><creator>Chen, Caiyou</creator><creator>Wang, Qian</creator><creator>Han, Zhengyu</creator><creator>Dong, Xiu-Qin</creator><creator>Zhang, Xumu</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160101</creationdate><title>New tetraphosphite ligands for regioselective linear hydroformylation of terminal and internal olefins</title><author>Zhang, Zongpeng ; Chen, Caiyou ; Wang, Qian ; Han, Zhengyu ; Dong, Xiu-Qin ; Zhang, Xumu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c330t-7f44a93999d23019fcd83d7302e07c150cee2909ec64d41e07e446d6da958c663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Catalysis</topic><topic>Conversion</topic><topic>Ligands</topic><topic>Olefins</topic><topic>Rhodium</topic><topic>Selectivity</topic><topic>Styrenes</topic><topic>Terminals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Zongpeng</creatorcontrib><creatorcontrib>Chen, Caiyou</creatorcontrib><creatorcontrib>Wang, Qian</creatorcontrib><creatorcontrib>Han, Zhengyu</creatorcontrib><creatorcontrib>Dong, Xiu-Qin</creatorcontrib><creatorcontrib>Zhang, Xumu</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Zongpeng</au><au>Chen, Caiyou</au><au>Wang, Qian</au><au>Han, Zhengyu</au><au>Dong, Xiu-Qin</au><au>Zhang, Xumu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New tetraphosphite ligands for regioselective linear hydroformylation of terminal and internal olefins</atitle><jtitle>RSC advances</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>6</volume><issue>18</issue><spage>14559</spage><epage>14562</epage><pages>14559-14562</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>We successfully developed new tetraphosphite ligands
L1–L5
and applied them to the rhodium-catalyzed hydroformylation of terminal and internal olefins. High catalytic reactivities and excellent regioselectivities for linear aldehydes were obtained in the rhodium-catalyzed hydroformylation of simple olefins (l/b ratio up to 90, 98.9% linear selectivity, 99.2% conversion) using the tetraphosphite ligand
L2
. And the tetraphosphite ligand
L2
also displayed moderate to good linear regioselectivities for challenging substrates styrene and internal olefin 2-octene.</abstract><doi>10.1039/C5RA23683E</doi><tpages>4</tpages></addata></record> |
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| ispartof | RSC advances, 2016-01, Vol.6 (18), p.14559-14562 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals |
| subjects | Catalysis Conversion Ligands Olefins Rhodium Selectivity Styrenes Terminals |
| title | New tetraphosphite ligands for regioselective linear hydroformylation of terminal and internal olefins |
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