Synthesis of Ladder-like Polyphenylsilsesquioxanes with Fairly High Regularity Using 1,2-Ethylenediamine as Endo-template
Ladder-like polyphenylsilsesquioxanes with fairly high regularity were synthesized using an endo-template 1,2-ethylenediamine at mild temperature via direct co-hydrolysis and condensation reactions in the presence of acid catalysts in the mixture of 1,4-dioxane/H20. The features for synthesis of lad...
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Veröffentlicht in: | Chinese journal of polymer science 2015-09, Vol.33 (9), p.1305-1312 |
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creator | Yang, Xiong-fa Cao, Cheng Chen, Zhong-hong Liu, Jia Luo, Meng-xian Lai, Guo-qiao |
description | Ladder-like polyphenylsilsesquioxanes with fairly high regularity were synthesized using an endo-template 1,2-ethylenediamine at mild temperature via direct co-hydrolysis and condensation reactions in the presence of acid catalysts in the mixture of 1,4-dioxane/H20. The features for synthesis of ladder-like polyphenylsilsesquioxanes were investigated in detail. The products obtained were characterized by FTIR, SEC, XRD and NMR. |
doi_str_mv | 10.1007/s10118-015-1678-z |
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The features for synthesis of ladder-like polyphenylsilsesquioxanes were investigated in detail. 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The features for synthesis of ladder-like polyphenylsilsesquioxanes were investigated in detail. 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subjects | Catalysis Catalysts Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensates Condensed Matter Physics Industrial Chemistry/Chemical Engineering Nuclear magnetic resonance Polymer Sciences Regularity Synthesis X射线衍射 乙二胺 二氧六环 模板合成 水解缩聚 美国证券交易委员会 酸催化剂 阶梯状 |
title | Synthesis of Ladder-like Polyphenylsilsesquioxanes with Fairly High Regularity Using 1,2-Ethylenediamine as Endo-template |
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