Chiral-at-metal iridium complex for efficient enantioselective transfer hydrogenation of ketones

A bis-cyclometalated iridium(III) complex with metal-centered chirality catalyzes the enantioselective transfer hydrogenation of ketones with high enantioselectivities at low catalyst loadings down to 0.002 mol%. Importantly, the rate of catalysis and enantioselectivity are markedly improved in the...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2016-03, Vol.52 (22), p.4207-4210
Hauptverfasser:	Tian, Cheng, Gong, Lei, Meggers, Eric
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Chirality Hydrogenation Iridium compounds Ketones Pyrazole
Online-Zugang:	Volltext
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