Highly diastereoselective approach to methylenecyclopropanes via boron-homologation/allylboration sequences

A simple and efficient diastereoselective synthesis of methylenecyclopropanes is described, in which boron-homologation and allylboration are merged into a one-pot process, starting from in situ generated cyclopropenyllithium species. This unprecedented methodology opens a new route to strained alky...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (12), p.2529-2532
Hauptverfasser:	Baumann, A N, Music, A, Karaghiosoff, K, Didier, D
Format:	Artikel
Sprache:	eng
Schlagworte:	Methodology Synthesis
Online-Zugang:	Volltext
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