Efficient Dispersion of “Super-Growth” Single-Walled Carbon Nanotubes Using a Copolymer of Naphathalene Diimide and Poly(dimethylsiloxane)
The dispersion of carbon nanotubes is a key issue for maximizing their performance in many applications. Here we describe the design and synthesis of an efficient dispersant for the so-called “super-growth” single-walled carbon nanotubes (SG-SWNTs) to provide a stable and homogeneous dispersion in t...
Gespeichert in:
| Veröffentlicht in: | Bulletin of the Chemical Society of Japan 2016, Vol.89 (2), p.183-191 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 191 |
|---|---|
| container_issue | 2 |
| container_start_page | 183 |
| container_title | Bulletin of the Chemical Society of Japan |
| container_volume | 89 |
| creator | Hong, Liu Takagaki, Yusaku Yoshikawa, Hitoshi Nakashima, Naotoshi |
| description | The dispersion of carbon nanotubes is a key issue for maximizing their performance in many applications. Here we describe the design and synthesis of an efficient dispersant for the so-called “super-growth” single-walled carbon nanotubes (SG-SWNTs) to provide a stable and homogeneous dispersion in typical organic solvents simply by sonication. The synthesized dispersant is a copolymer composed of a naphthalene diimide and poly(dimethylsiloxane), and the dispersions were characterized using visible absorption, Raman, AFM, and TGA measurements as well as molecular-mechanics simulations. It was found that the copolymer efficiently dissolves the SG-SWNTs in many solvents including methyl ethyl ketone, methyl isobutyl ketone, and toluene that are widely-used solvents in polymer/resin-related industrial areas. |
| doi_str_mv | 10.1246/bcsj.20150340 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1800452534</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3972787411</sourcerecordid><originalsourceid>FETCH-LOGICAL-c543t-1197a1b7dd1bdc1d054324efb41a68a1de1565354e36f4401385077eb241dfb3</originalsourceid><addsrcrecordid>eNptkc1u1TAQha0KJC6lS_aW2LSLFE9s54cdui0FqSpILWIZOfGk8ZVjp3YiuLs-AU8AL9cnqa9apKpiNZqZb84Z6RDyFtgx5KJ433Zxc5wzkIwLtkdWwEWVsYKLF2TFGKuzvCj5K_I6xk1qKynqFfl92vemM-hmemLihCEa76jv6d3tn8sl9dlZ8D_n4e72L7007tpi9kNZi5quVWgTeqGcn5cWI_0e054quvaTt9sRw07mQk2Dmgdl0WFyMKPRSJXT9FtiDrUZcR62NhrrfymHR2_Iy17ZiAePdZ9cfTq9Wn_Ozr-efVl_PM86KficAdSlgrbUGlrdgWZpmgvsWwGqqBRoBFlILgXyoheCAa8kK0tscwG6b_k-OXyQnYK_WTDOzWhih9amH_wSG6gYEzKXXCT03TN045fg0nMNlCWrC8ZrmajsgeqCjzFg30zBjCpsG2DNLpxmF07zL5zEf3jkBxxNl9R8CmHebtSk3BOH_x7fA0qFmVI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1770960395</pqid></control><display><type>article</type><title>Efficient Dispersion of “Super-Growth” Single-Walled Carbon Nanotubes Using a Copolymer of Naphathalene Diimide and Poly(dimethylsiloxane)</title><source>Oxford University Press Journals All Titles (1996-Current)</source><creator>Hong, Liu ; Takagaki, Yusaku ; Yoshikawa, Hitoshi ; Nakashima, Naotoshi</creator><creatorcontrib>Hong, Liu ; Takagaki, Yusaku ; Yoshikawa, Hitoshi ; Nakashima, Naotoshi</creatorcontrib><description>The dispersion of carbon nanotubes is a key issue for maximizing their performance in many applications. Here we describe the design and synthesis of an efficient dispersant for the so-called “super-growth” single-walled carbon nanotubes (SG-SWNTs) to provide a stable and homogeneous dispersion in typical organic solvents simply by sonication. The synthesized dispersant is a copolymer composed of a naphthalene diimide and poly(dimethylsiloxane), and the dispersions were characterized using visible absorption, Raman, AFM, and TGA measurements as well as molecular-mechanics simulations. It was found that the copolymer efficiently dissolves the SG-SWNTs in many solvents including methyl ethyl ketone, methyl isobutyl ketone, and toluene that are widely-used solvents in polymer/resin-related industrial areas.</description><identifier>ISSN: 0009-2673</identifier><identifier>EISSN: 1348-0634</identifier><identifier>DOI: 10.1246/bcsj.20150340</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><subject>Copolymers ; Diimide ; Dispersants ; Dispersions ; Simulation ; Single wall carbon nanotubes ; Solvents ; Toluene</subject><ispartof>Bulletin of the Chemical Society of Japan, 2016, Vol.89 (2), p.183-191</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c543t-1197a1b7dd1bdc1d054324efb41a68a1de1565354e36f4401385077eb241dfb3</citedby><cites>FETCH-LOGICAL-c543t-1197a1b7dd1bdc1d054324efb41a68a1de1565354e36f4401385077eb241dfb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Hong, Liu</creatorcontrib><creatorcontrib>Takagaki, Yusaku</creatorcontrib><creatorcontrib>Yoshikawa, Hitoshi</creatorcontrib><creatorcontrib>Nakashima, Naotoshi</creatorcontrib><title>Efficient Dispersion of “Super-Growth” Single-Walled Carbon Nanotubes Using a Copolymer of Naphathalene Diimide and Poly(dimethylsiloxane)</title><title>Bulletin of the Chemical Society of Japan</title><addtitle>Bulletin of the Chemical Society of Japan</addtitle><description>The dispersion of carbon nanotubes is a key issue for maximizing their performance in many applications. Here we describe the design and synthesis of an efficient dispersant for the so-called “super-growth” single-walled carbon nanotubes (SG-SWNTs) to provide a stable and homogeneous dispersion in typical organic solvents simply by sonication. The synthesized dispersant is a copolymer composed of a naphthalene diimide and poly(dimethylsiloxane), and the dispersions were characterized using visible absorption, Raman, AFM, and TGA measurements as well as molecular-mechanics simulations. It was found that the copolymer efficiently dissolves the SG-SWNTs in many solvents including methyl ethyl ketone, methyl isobutyl ketone, and toluene that are widely-used solvents in polymer/resin-related industrial areas.</description><subject>Copolymers</subject><subject>Diimide</subject><subject>Dispersants</subject><subject>Dispersions</subject><subject>Simulation</subject><subject>Single wall carbon nanotubes</subject><subject>Solvents</subject><subject>Toluene</subject><issn>0009-2673</issn><issn>1348-0634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNptkc1u1TAQha0KJC6lS_aW2LSLFE9s54cdui0FqSpILWIZOfGk8ZVjp3YiuLs-AU8AL9cnqa9apKpiNZqZb84Z6RDyFtgx5KJ433Zxc5wzkIwLtkdWwEWVsYKLF2TFGKuzvCj5K_I6xk1qKynqFfl92vemM-hmemLihCEa76jv6d3tn8sl9dlZ8D_n4e72L7007tpi9kNZi5quVWgTeqGcn5cWI_0e054quvaTt9sRw07mQk2Dmgdl0WFyMKPRSJXT9FtiDrUZcR62NhrrfymHR2_Iy17ZiAePdZ9cfTq9Wn_Ozr-efVl_PM86KficAdSlgrbUGlrdgWZpmgvsWwGqqBRoBFlILgXyoheCAa8kK0tscwG6b_k-OXyQnYK_WTDOzWhih9amH_wSG6gYEzKXXCT03TN045fg0nMNlCWrC8ZrmajsgeqCjzFg30zBjCpsG2DNLpxmF07zL5zEf3jkBxxNl9R8CmHebtSk3BOH_x7fA0qFmVI</recordid><startdate>2016</startdate><enddate>2016</enddate><creator>Hong, Liu</creator><creator>Takagaki, Yusaku</creator><creator>Yoshikawa, Hitoshi</creator><creator>Nakashima, Naotoshi</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>2016</creationdate><title>Efficient Dispersion of “Super-Growth” Single-Walled Carbon Nanotubes Using a Copolymer of Naphathalene Diimide and Poly(dimethylsiloxane)</title><author>Hong, Liu ; Takagaki, Yusaku ; Yoshikawa, Hitoshi ; Nakashima, Naotoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c543t-1197a1b7dd1bdc1d054324efb41a68a1de1565354e36f4401385077eb241dfb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Copolymers</topic><topic>Diimide</topic><topic>Dispersants</topic><topic>Dispersions</topic><topic>Simulation</topic><topic>Single wall carbon nanotubes</topic><topic>Solvents</topic><topic>Toluene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hong, Liu</creatorcontrib><creatorcontrib>Takagaki, Yusaku</creatorcontrib><creatorcontrib>Yoshikawa, Hitoshi</creatorcontrib><creatorcontrib>Nakashima, Naotoshi</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Bulletin of the Chemical Society of Japan</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hong, Liu</au><au>Takagaki, Yusaku</au><au>Yoshikawa, Hitoshi</au><au>Nakashima, Naotoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient Dispersion of “Super-Growth” Single-Walled Carbon Nanotubes Using a Copolymer of Naphathalene Diimide and Poly(dimethylsiloxane)</atitle><jtitle>Bulletin of the Chemical Society of Japan</jtitle><addtitle>Bulletin of the Chemical Society of Japan</addtitle><date>2016</date><risdate>2016</risdate><volume>89</volume><issue>2</issue><spage>183</spage><epage>191</epage><pages>183-191</pages><issn>0009-2673</issn><eissn>1348-0634</eissn><abstract>The dispersion of carbon nanotubes is a key issue for maximizing their performance in many applications. Here we describe the design and synthesis of an efficient dispersant for the so-called “super-growth” single-walled carbon nanotubes (SG-SWNTs) to provide a stable and homogeneous dispersion in typical organic solvents simply by sonication. The synthesized dispersant is a copolymer composed of a naphthalene diimide and poly(dimethylsiloxane), and the dispersions were characterized using visible absorption, Raman, AFM, and TGA measurements as well as molecular-mechanics simulations. It was found that the copolymer efficiently dissolves the SG-SWNTs in many solvents including methyl ethyl ketone, methyl isobutyl ketone, and toluene that are widely-used solvents in polymer/resin-related industrial areas.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/bcsj.20150340</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0009-2673 |
| ispartof | Bulletin of the Chemical Society of Japan, 2016, Vol.89 (2), p.183-191 |
| issn | 0009-2673 1348-0634 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1800452534 |
| source | Oxford University Press Journals All Titles (1996-Current) |
| subjects | Copolymers Diimide Dispersants Dispersions Simulation Single wall carbon nanotubes Solvents Toluene |
| title | Efficient Dispersion of “Super-Growth” Single-Walled Carbon Nanotubes Using a Copolymer of Naphathalene Diimide and Poly(dimethylsiloxane) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T03%3A38%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Efficient%20Dispersion%20of%20%E2%80%9CSuper-Growth%E2%80%9D%20Single-Walled%20Carbon%20Nanotubes%20Using%20a%20Copolymer%20of%20Naphathalene%20Diimide%20and%20Poly(dimethylsiloxane)&rft.jtitle=Bulletin%20of%20the%20Chemical%20Society%20of%20Japan&rft.au=Hong,%20Liu&rft.date=2016&rft.volume=89&rft.issue=2&rft.spage=183&rft.epage=191&rft.pages=183-191&rft.issn=0009-2673&rft.eissn=1348-0634&rft_id=info:doi/10.1246/bcsj.20150340&rft_dat=%3Cproquest_cross%3E3972787411%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1770960395&rft_id=info:pmid/&rfr_iscdi=true |