Extraction of rare-earth elements(III) from nitric acid solutions with bis(diarylphosphorylmethyl)benzenes

Extraction of micro quantities of rare-earth elements(III) from HNO 3 solutions as complexes with bis (diarylphosphorylmethyl)benzenes depending on the nature of organic diluent and HNO 3 concentration in equilibrium aqueous phase was studied, the stoichiometry of extracted complexes was determined....

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Veröffentlicht in:Russian journal of inorganic chemistry 2015-08, Vol.60 (8), p.1015-1021
Hauptverfasser: Turanov, A. N., Karandashev, V. K., Baulin, V. E., Kirillov, E. V., Kirillov, S. V., Rychkov, V. N., Tsivadze, A. Yu
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container_end_page 1021
container_issue 8
container_start_page 1015
container_title Russian journal of inorganic chemistry
container_volume 60
creator Turanov, A. N.
Karandashev, V. K.
Baulin, V. E.
Kirillov, E. V.
Kirillov, S. V.
Rychkov, V. N.
Tsivadze, A. Yu
description Extraction of micro quantities of rare-earth elements(III) from HNO 3 solutions as complexes with bis (diarylphosphorylmethyl)benzenes depending on the nature of organic diluent and HNO 3 concentration in equilibrium aqueous phase was studied, the stoichiometry of extracted complexes was determined. The effect of structure of a bridge between two phosphine oxide fragments in an extractant molecule on the efficiency and selectivity of rare-earth elements(III) extraction was considered.
doi_str_mv 10.1134/S0036023615080203
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1531-8613
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subjects Bridges (structures)
Chemistry
Chemistry and Materials Science
Extraction
Inorganic Chemistry
Molecular structure
Nitric acid
Phosphine oxide
Physical Chemistry of Solutions
Rare earth metals
Selectivity
Stoichiometry
title Extraction of rare-earth elements(III) from nitric acid solutions with bis(diarylphosphorylmethyl)benzenes
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