Extraction of rare-earth elements(III) from nitric acid solutions with bis(diarylphosphorylmethyl)benzenes
Extraction of micro quantities of rare-earth elements(III) from HNO 3 solutions as complexes with bis (diarylphosphorylmethyl)benzenes depending on the nature of organic diluent and HNO 3 concentration in equilibrium aqueous phase was studied, the stoichiometry of extracted complexes was determined....
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Veröffentlicht in: | Russian journal of inorganic chemistry 2015-08, Vol.60 (8), p.1015-1021 |
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container_title | Russian journal of inorganic chemistry |
container_volume | 60 |
creator | Turanov, A. N. Karandashev, V. K. Baulin, V. E. Kirillov, E. V. Kirillov, S. V. Rychkov, V. N. Tsivadze, A. Yu |
description | Extraction of micro quantities of rare-earth elements(III) from HNO
3
solutions as complexes with
bis
(diarylphosphorylmethyl)benzenes depending on the nature of organic diluent and HNO
3
concentration in equilibrium aqueous phase was studied, the stoichiometry of extracted complexes was determined. The effect of structure of a bridge between two phosphine oxide fragments in an extractant molecule on the efficiency and selectivity of rare-earth elements(III) extraction was considered. |
doi_str_mv | 10.1134/S0036023615080203 |
format | Article |
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3
solutions as complexes with
bis
(diarylphosphorylmethyl)benzenes depending on the nature of organic diluent and HNO
3
concentration in equilibrium aqueous phase was studied, the stoichiometry of extracted complexes was determined. The effect of structure of a bridge between two phosphine oxide fragments in an extractant molecule on the efficiency and selectivity of rare-earth elements(III) extraction was considered.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023615080203</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Bridges (structures) ; Chemistry ; Chemistry and Materials Science ; Extraction ; Inorganic Chemistry ; Molecular structure ; Nitric acid ; Phosphine oxide ; Physical Chemistry of Solutions ; Rare earth metals ; Selectivity ; Stoichiometry</subject><ispartof>Russian journal of inorganic chemistry, 2015-08, Vol.60 (8), p.1015-1021</ispartof><rights>Pleiades Publishing, Ltd. 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321t-ea8f12bfa679a337fa90ec6455cd503f157e54d5bd6c02ce549fa60ab85ba04a3</citedby><cites>FETCH-LOGICAL-c321t-ea8f12bfa679a337fa90ec6455cd503f157e54d5bd6c02ce549fa60ab85ba04a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023615080203$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023615080203$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Turanov, A. N.</creatorcontrib><creatorcontrib>Karandashev, V. K.</creatorcontrib><creatorcontrib>Baulin, V. E.</creatorcontrib><creatorcontrib>Kirillov, E. V.</creatorcontrib><creatorcontrib>Kirillov, S. V.</creatorcontrib><creatorcontrib>Rychkov, V. N.</creatorcontrib><creatorcontrib>Tsivadze, A. Yu</creatorcontrib><title>Extraction of rare-earth elements(III) from nitric acid solutions with bis(diarylphosphorylmethyl)benzenes</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>Extraction of micro quantities of rare-earth elements(III) from HNO
3
solutions as complexes with
bis
(diarylphosphorylmethyl)benzenes depending on the nature of organic diluent and HNO
3
concentration in equilibrium aqueous phase was studied, the stoichiometry of extracted complexes was determined. The effect of structure of a bridge between two phosphine oxide fragments in an extractant molecule on the efficiency and selectivity of rare-earth elements(III) extraction was considered.</description><subject>Bridges (structures)</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Extraction</subject><subject>Inorganic Chemistry</subject><subject>Molecular structure</subject><subject>Nitric acid</subject><subject>Phosphine oxide</subject><subject>Physical Chemistry of Solutions</subject><subject>Rare earth metals</subject><subject>Selectivity</subject><subject>Stoichiometry</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEqXwAey8bBeBcRznsURVgUqVWADryHHG1FUSF9sRj6_HUdkhsRjNSPfcGd0h5JrBDWM8u30G4DmkPGcCSkiBn5AZE5wlZc74KZlNcjLp5-TC-z1AlkFRzsh-_RmcVMHYgVpNnXSYoHRhR7HDHofgF5vNZkm1sz0dTHBGUalMS73txsnl6YeJdGP8ojXSfXWHnfWx4tRj2H11ywaHbxzQX5IzLTuPV799Tl7v1y-rx2T79LBZ3W0TxVMW4vVSs7TRMi8qyXmhZQWo8kwI1QrgmokCRdaKps0VpCrOVWRBNqVoJGSSz8niuPfg7PuIPtS98Qq7Tg5oR1-zckpfVFkVUXZElbPeO9T1wZk-pqgZ1NNf6z9_jZ706PGRHd7Q1Xs7uiEm-sf0A4cPfAQ</recordid><startdate>20150801</startdate><enddate>20150801</enddate><creator>Turanov, A. N.</creator><creator>Karandashev, V. K.</creator><creator>Baulin, V. E.</creator><creator>Kirillov, E. V.</creator><creator>Kirillov, S. V.</creator><creator>Rychkov, V. N.</creator><creator>Tsivadze, A. Yu</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150801</creationdate><title>Extraction of rare-earth elements(III) from nitric acid solutions with bis(diarylphosphorylmethyl)benzenes</title><author>Turanov, A. N. ; Karandashev, V. K. ; Baulin, V. E. ; Kirillov, E. V. ; Kirillov, S. V. ; Rychkov, V. N. ; Tsivadze, A. Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321t-ea8f12bfa679a337fa90ec6455cd503f157e54d5bd6c02ce549fa60ab85ba04a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Bridges (structures)</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Extraction</topic><topic>Inorganic Chemistry</topic><topic>Molecular structure</topic><topic>Nitric acid</topic><topic>Phosphine oxide</topic><topic>Physical Chemistry of Solutions</topic><topic>Rare earth metals</topic><topic>Selectivity</topic><topic>Stoichiometry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Turanov, A. N.</creatorcontrib><creatorcontrib>Karandashev, V. K.</creatorcontrib><creatorcontrib>Baulin, V. E.</creatorcontrib><creatorcontrib>Kirillov, E. V.</creatorcontrib><creatorcontrib>Kirillov, S. V.</creatorcontrib><creatorcontrib>Rychkov, V. N.</creatorcontrib><creatorcontrib>Tsivadze, A. Yu</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Turanov, A. N.</au><au>Karandashev, V. K.</au><au>Baulin, V. E.</au><au>Kirillov, E. V.</au><au>Kirillov, S. V.</au><au>Rychkov, V. N.</au><au>Tsivadze, A. Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Extraction of rare-earth elements(III) from nitric acid solutions with bis(diarylphosphorylmethyl)benzenes</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2015-08-01</date><risdate>2015</risdate><volume>60</volume><issue>8</issue><spage>1015</spage><epage>1021</epage><pages>1015-1021</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>Extraction of micro quantities of rare-earth elements(III) from HNO
3
solutions as complexes with
bis
(diarylphosphorylmethyl)benzenes depending on the nature of organic diluent and HNO
3
concentration in equilibrium aqueous phase was studied, the stoichiometry of extracted complexes was determined. The effect of structure of a bridge between two phosphine oxide fragments in an extractant molecule on the efficiency and selectivity of rare-earth elements(III) extraction was considered.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023615080203</doi><tpages>7</tpages></addata></record> |
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language | eng |
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subjects | Bridges (structures) Chemistry Chemistry and Materials Science Extraction Inorganic Chemistry Molecular structure Nitric acid Phosphine oxide Physical Chemistry of Solutions Rare earth metals Selectivity Stoichiometry |
title | Extraction of rare-earth elements(III) from nitric acid solutions with bis(diarylphosphorylmethyl)benzenes |
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