Recent Advances in Catalytic Asymmetric C–C Bond-Forming Reactions to Ketimines Promoted by Metal-Based Catalysts

Recent progress (post-2010) in the field of metal-catalyzed asymmetric C–C bond-forming reactions using ketimines as electrophiles is reviewed. Compared with the corresponding aldimines, ketimines generally display less inherent reactivity and the two substituents on the imine carbon hamper prochira...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2015-04, Vol.88 (4), p.503-517
Hauptverfasser:	Kumagai, Naoya, Shibasaki, Masakatsu
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetry Bonding Carbon Carbon-carbon composites Catalysis Catalysts Chemical reactions Imines
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container_title	Bulletin of the Chemical Society of Japan
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creator	Kumagai, Naoya Shibasaki, Masakatsu
description	Recent progress (post-2010) in the field of metal-catalyzed asymmetric C–C bond-forming reactions using ketimines as electrophiles is reviewed. Compared with the corresponding aldimines, ketimines generally display less inherent reactivity and the two substituents on the imine carbon hamper prochiral-face-selection for enantioselective reactions. Recent advances with newly developed catalytic systems have resulted in several solutions to these long-standing problems. The construction of tetrasubstituted stereogenic centers is a crucial topic of asymmetric catalysis in the 21st century, and it is becoming increasingly clear that reactions using ketimines as electrophiles become one of the most important routes to access such chemical entities.
doi_str_mv	10.1246/bcsj.20140302
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Asymmetry Bonding Carbon Carbon-carbon composites Catalysis Catalysts Chemical reactions Imines
title	Recent Advances in Catalytic Asymmetric C–C Bond-Forming Reactions to Ketimines Promoted by Metal-Based Catalysts
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