On the Origin and Structure of the Recently Observed Acetal in the Soai Reaction
Recent observation of the acetal species in the course of autoamplifying Soai reaction was analysed by the formal kinetic analysis of the experimental data and DFT computations. Kinetic analysis demonstrated convincingly that the observed species cannot be a precursor of the reaction product. Hence,...
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| Veröffentlicht in: | Bulletin of the Chemical Society of Japan 2015-02, Vol.88 (2), p.333-340 |
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| container_end_page | 340 |
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| container_title | Bulletin of the Chemical Society of Japan |
| container_volume | 88 |
| creator | D Gridnev, Ilya Kh Vorobiev, Andrey |
| description | Recent observation of the acetal species in the course of autoamplifying Soai reaction was analysed by the formal kinetic analysis of the experimental data and DFT computations. Kinetic analysis demonstrated convincingly that the observed species cannot be a precursor of the reaction product. Hence, it is an off-loop species that is not important for the process of the chirality amplification. DFT search for a kinetically stable acetal species resulted in the location of a Zn3 cluster stabilized with three Zn–O–Zn bridges. |
| doi_str_mv | 10.1246/bcsj.20140341 |
| format | Article |
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Kinetic analysis demonstrated convincingly that the observed species cannot be a precursor of the reaction product. Hence, it is an off-loop species that is not important for the process of the chirality amplification. DFT search for a kinetically stable acetal species resulted in the location of a Zn3 cluster stabilized with three Zn–O–Zn bridges.</description><identifier>ISSN: 0009-2673</identifier><identifier>EISSN: 1348-0634</identifier><identifier>DOI: 10.1246/bcsj.20140341</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><subject>Amplification ; Chirality ; Clusters ; Origins ; Precursors ; Reaction kinetics ; Searching ; Zinc</subject><ispartof>Bulletin of the Chemical Society of Japan, 2015-02, Vol.88 (2), p.333-340</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c486t-c8376c167ac8b207872211463fb92525f3cc9ca8e2bc1ca3bc6a9818f7e97bb33</citedby><cites>FETCH-LOGICAL-c486t-c8376c167ac8b207872211463fb92525f3cc9ca8e2bc1ca3bc6a9818f7e97bb33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>D Gridnev, Ilya</creatorcontrib><creatorcontrib>Kh Vorobiev, Andrey</creatorcontrib><title>On the Origin and Structure of the Recently Observed Acetal in the Soai Reaction</title><title>Bulletin of the Chemical Society of Japan</title><addtitle>Bulletin of the Chemical Society of Japan</addtitle><description>Recent observation of the acetal species in the course of autoamplifying Soai reaction was analysed by the formal kinetic analysis of the experimental data and DFT computations. 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| ispartof | Bulletin of the Chemical Society of Japan, 2015-02, Vol.88 (2), p.333-340 |
| issn | 0009-2673 1348-0634 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1800444301 |
| source | Oxford University Press Journals All Titles (1996-Current) |
| subjects | Amplification Chirality Clusters Origins Precursors Reaction kinetics Searching Zinc |
| title | On the Origin and Structure of the Recently Observed Acetal in the Soai Reaction |
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