A general and direct synthesis of imidazolium ionic liquids using orthoesters

A general method to synthesize halide and halide-free ionic liquids was developed. Direct alkylation of imidazole and pyridine derivatives was performed in the presence of an acid using an orthoester as the alkyl donor yielding ionic liquid products. Residual Cl and water contents of the ionic liqui...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2014, Vol.16 (9), p.4098-4101
Hauptverfasser: Kim, Do Joong, Oh, Kyung Hwan, Park, Jin Kyoon
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container_title Green chemistry : an international journal and green chemistry resource : GC
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creator Kim, Do Joong
Oh, Kyung Hwan
Park, Jin Kyoon
description A general method to synthesize halide and halide-free ionic liquids was developed. Direct alkylation of imidazole and pyridine derivatives was performed in the presence of an acid using an orthoester as the alkyl donor yielding ionic liquid products. Residual Cl and water contents of the ionic liquids were determined by ion chromatography and a Karl-Fisher test.
doi_str_mv 10.1039/c4gc00684d
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identifier ISSN: 1463-9262
ispartof Green chemistry : an international journal and green chemistry resource : GC, 2014, Vol.16 (9), p.4098-4101
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1463-9270
language eng
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chromatography
Derivatives
Halides
Imidazole
Ionic liquids
Moisture content
Pyridines
Synthesis
title A general and direct synthesis of imidazolium ionic liquids using orthoesters
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