Synthesis and structure of tetra- and triphenylantimony phenylpropiolates
Tetraphenylantimony phenylpropiolate ( I ) has been synthesized by the reaction between pentaphenylantimony and phenylpropiolic acid or triphenylantimony bis(phenylpropiolate) in toluene. Triphenylantimony bis(phenylpropiolate) ( II ) has been synthesized from triphenylantimony and phenylpropiolic a...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2015-04, Vol.60 (4), p.465-468 |
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| creator | Sharutin, V. V. Sharutina, O. K. Kotlyarov, A. R. |
| description | Tetraphenylantimony phenylpropiolate (
I
) has been synthesized by the reaction between pentaphenylantimony and phenylpropiolic acid or triphenylantimony bis(phenylpropiolate) in toluene. Triphenylantimony bis(phenylpropiolate) (
II
) has been synthesized from triphenylantimony and phenylpropiolic acid in ether in the presence of
tert
-butylhydroperoxide. According to X-ray diffraction data, the antimony atoms in complexes
I
and
II
are in a trigonal bipyramidal coordination, and the axial CSbO and OSbO angles are 178.63(7)° and 177.68(7)°. The Sb-C and Sb-O bond lengths and the equatorial CSbC angles are 2.120(3)–2.166(3) and 2.267(2) Å, and 113.44°, 114.80°, and 128.12° (
I
) and 2.104(2)–2.109(3) and 2.136(2) Å and 108.38°, 108.38°, and 143.23° (
II
), respectively. Sb⋯O=(C) intramolecular contacts are 3.357(3) Å (
I
) and 2.919(5) Å (
II
). |
| doi_str_mv | 10.1134/S0036023615040221 |
| format | Article |
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I
) has been synthesized by the reaction between pentaphenylantimony and phenylpropiolic acid or triphenylantimony bis(phenylpropiolate) in toluene. Triphenylantimony bis(phenylpropiolate) (
II
) has been synthesized from triphenylantimony and phenylpropiolic acid in ether in the presence of
tert
-butylhydroperoxide. According to X-ray diffraction data, the antimony atoms in complexes
I
and
II
are in a trigonal bipyramidal coordination, and the axial CSbO and OSbO angles are 178.63(7)° and 177.68(7)°. The Sb-C and Sb-O bond lengths and the equatorial CSbC angles are 2.120(3)–2.166(3) and 2.267(2) Å, and 113.44°, 114.80°, and 128.12° (
I
) and 2.104(2)–2.109(3) and 2.136(2) Å and 108.38°, 108.38°, and 143.23° (
II
), respectively. Sb⋯O=(C) intramolecular contacts are 3.357(3) Å (
I
) and 2.919(5) Å (
II
).</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023615040221</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Antimony ; Bonding ; Chemistry ; Chemistry and Materials Science ; Contact ; Coordination Compounds ; Diffraction ; Ethers ; Inorganic Chemistry ; Synthesis ; Toluene ; X-rays</subject><ispartof>Russian journal of inorganic chemistry, 2015-04, Vol.60 (4), p.465-468</ispartof><rights>Pleiades Publishing, Ltd. 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321t-6e7ae35814f86fa60248c87d314c01cb38fe79e047a89ed9f0d693b7a0ea83503</citedby><cites>FETCH-LOGICAL-c321t-6e7ae35814f86fa60248c87d314c01cb38fe79e047a89ed9f0d693b7a0ea83503</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023615040221$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023615040221$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Sharutin, V. V.</creatorcontrib><creatorcontrib>Sharutina, O. K.</creatorcontrib><creatorcontrib>Kotlyarov, A. R.</creatorcontrib><title>Synthesis and structure of tetra- and triphenylantimony phenylpropiolates</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>Tetraphenylantimony phenylpropiolate (
I
) has been synthesized by the reaction between pentaphenylantimony and phenylpropiolic acid or triphenylantimony bis(phenylpropiolate) in toluene. Triphenylantimony bis(phenylpropiolate) (
II
) has been synthesized from triphenylantimony and phenylpropiolic acid in ether in the presence of
tert
-butylhydroperoxide. According to X-ray diffraction data, the antimony atoms in complexes
I
and
II
are in a trigonal bipyramidal coordination, and the axial CSbO and OSbO angles are 178.63(7)° and 177.68(7)°. The Sb-C and Sb-O bond lengths and the equatorial CSbC angles are 2.120(3)–2.166(3) and 2.267(2) Å, and 113.44°, 114.80°, and 128.12° (
I
) and 2.104(2)–2.109(3) and 2.136(2) Å and 108.38°, 108.38°, and 143.23° (
II
), respectively. Sb⋯O=(C) intramolecular contacts are 3.357(3) Å (
I
) and 2.919(5) Å (
II
).</description><subject>Antimony</subject><subject>Bonding</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Contact</subject><subject>Coordination Compounds</subject><subject>Diffraction</subject><subject>Ethers</subject><subject>Inorganic Chemistry</subject><subject>Synthesis</subject><subject>Toluene</subject><subject>X-rays</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9UE1PhDAQbYwmrqs_wBtHL-gMLaUczcaPTTbxsHomXRhcNlCwLQf-vUW8mXiazLz3ZuY9xm4R7hG5eNgDcAkJl5iCgCTBM7bClGOsJPJztprheMYv2ZVzJwAhIFMrtt1Pxh_JNS7Spoqct2PpR0tRX0eevNXxz9zbZjiSmVptfNP1ZoqWdrD90PSt9uSu2UWtW0c3v3XNPp6f3jev8e7tZbt53MUlT9DHkjJNPFUoaiVrHX4WqlRZxVGUgOWBq5qynEBkWuVU5TVUMueHTANpxVPga3a37A23v0ZyvugaV1IbXqN-dAWqYG4mykDFhVra3jlLdTHYptN2KhCKObbiT2xBkywaF7jmk2xx6kdrgqN_RN-GOG9N</recordid><startdate>20150401</startdate><enddate>20150401</enddate><creator>Sharutin, V. V.</creator><creator>Sharutina, O. K.</creator><creator>Kotlyarov, A. R.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150401</creationdate><title>Synthesis and structure of tetra- and triphenylantimony phenylpropiolates</title><author>Sharutin, V. V. ; Sharutina, O. K. ; Kotlyarov, A. R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321t-6e7ae35814f86fa60248c87d314c01cb38fe79e047a89ed9f0d693b7a0ea83503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Antimony</topic><topic>Bonding</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Contact</topic><topic>Coordination Compounds</topic><topic>Diffraction</topic><topic>Ethers</topic><topic>Inorganic Chemistry</topic><topic>Synthesis</topic><topic>Toluene</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sharutin, V. V.</creatorcontrib><creatorcontrib>Sharutina, O. K.</creatorcontrib><creatorcontrib>Kotlyarov, A. R.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sharutin, V. V.</au><au>Sharutina, O. K.</au><au>Kotlyarov, A. R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and structure of tetra- and triphenylantimony phenylpropiolates</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2015-04-01</date><risdate>2015</risdate><volume>60</volume><issue>4</issue><spage>465</spage><epage>468</epage><pages>465-468</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>Tetraphenylantimony phenylpropiolate (
I
) has been synthesized by the reaction between pentaphenylantimony and phenylpropiolic acid or triphenylantimony bis(phenylpropiolate) in toluene. Triphenylantimony bis(phenylpropiolate) (
II
) has been synthesized from triphenylantimony and phenylpropiolic acid in ether in the presence of
tert
-butylhydroperoxide. According to X-ray diffraction data, the antimony atoms in complexes
I
and
II
are in a trigonal bipyramidal coordination, and the axial CSbO and OSbO angles are 178.63(7)° and 177.68(7)°. The Sb-C and Sb-O bond lengths and the equatorial CSbC angles are 2.120(3)–2.166(3) and 2.267(2) Å, and 113.44°, 114.80°, and 128.12° (
I
) and 2.104(2)–2.109(3) and 2.136(2) Å and 108.38°, 108.38°, and 143.23° (
II
), respectively. Sb⋯O=(C) intramolecular contacts are 3.357(3) Å (
I
) and 2.919(5) Å (
II
).</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023615040221</doi><tpages>4</tpages></addata></record> |
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| language | eng |
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| subjects | Antimony Bonding Chemistry Chemistry and Materials Science Contact Coordination Compounds Diffraction Ethers Inorganic Chemistry Synthesis Toluene X-rays |
| title | Synthesis and structure of tetra- and triphenylantimony phenylpropiolates |
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