Solubility of climbazole in various alcohols at different temperatures
•Solubility data of climbazole in various alcohols were measured.•The experimental data were correlated with NRTL, UNIQUAC and Wilson models.•The data are fit well with all three models for the six pure alcohols studied. (Solid+liquid) equilibria for climbazole in various alcohols (ethanol, 1-propan...
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| Veröffentlicht in: | The Journal of chemical thermodynamics 2014-10, Vol.77, p.1-6 |
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| container_title | The Journal of chemical thermodynamics |
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| creator | Kim, Hakmin Lim, Junhyuk Hong, Jung Hyun Kim, Ah Reum Shin, Moon Sam Kim, Hwayong |
| description | •Solubility data of climbazole in various alcohols were measured.•The experimental data were correlated with NRTL, UNIQUAC and Wilson models.•The data are fit well with all three models for the six pure alcohols studied.
(Solid+liquid) equilibria for climbazole in various alcohols (ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-heptanol) were investigated. The solubility data for climbazole in pure alcohols were obtained at temperatures ranging from (278.15 to 318.15)K. The melting temperature and fusion enthalpy of climbazole were measured using a differential scanning calorimeter (TA instrument Q100) and the experimental solubility was determined by the gravimetric method. The experimental solubility data were correlated by the equation for solubility of a solid in a liquid, and the activity coefficients were estimated by a non-random two liquid (NRTL), universal quasi-chemical (UNIQUAC), and Wilson models. |
| doi_str_mv | 10.1016/j.jct.2014.04.011 |
| format | Article |
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(Solid+liquid) equilibria for climbazole in various alcohols (ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-heptanol) were investigated. The solubility data for climbazole in pure alcohols were obtained at temperatures ranging from (278.15 to 318.15)K. The melting temperature and fusion enthalpy of climbazole were measured using a differential scanning calorimeter (TA instrument Q100) and the experimental solubility was determined by the gravimetric method. The experimental solubility data were correlated by the equation for solubility of a solid in a liquid, and the activity coefficients were estimated by a non-random two liquid (NRTL), universal quasi-chemical (UNIQUAC), and Wilson models.</description><identifier>ISSN: 0021-9614</identifier><identifier>EISSN: 1096-3626</identifier><identifier>DOI: 10.1016/j.jct.2014.04.011</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>(Solid + liquid) equilibrium ; Alcohols ; Climbazole ; Correlation ; Ethanol ; Ethyl alcohol ; Liquids ; Mathematical analysis ; Melting ; Scanning ; Solubility</subject><ispartof>The Journal of chemical thermodynamics, 2014-10, Vol.77, p.1-6</ispartof><rights>2014 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c330t-71836bf3f1f7fd31ae8ecbcc57ea3b4c09df2150251389423a574a6e6f65da603</citedby><cites>FETCH-LOGICAL-c330t-71836bf3f1f7fd31ae8ecbcc57ea3b4c09df2150251389423a574a6e6f65da603</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jct.2014.04.011$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27907,27908,45978</link.rule.ids></links><search><creatorcontrib>Kim, Hakmin</creatorcontrib><creatorcontrib>Lim, Junhyuk</creatorcontrib><creatorcontrib>Hong, Jung Hyun</creatorcontrib><creatorcontrib>Kim, Ah Reum</creatorcontrib><creatorcontrib>Shin, Moon Sam</creatorcontrib><creatorcontrib>Kim, Hwayong</creatorcontrib><title>Solubility of climbazole in various alcohols at different temperatures</title><title>The Journal of chemical thermodynamics</title><description>•Solubility data of climbazole in various alcohols were measured.•The experimental data were correlated with NRTL, UNIQUAC and Wilson models.•The data are fit well with all three models for the six pure alcohols studied.
(Solid+liquid) equilibria for climbazole in various alcohols (ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-heptanol) were investigated. The solubility data for climbazole in pure alcohols were obtained at temperatures ranging from (278.15 to 318.15)K. The melting temperature and fusion enthalpy of climbazole were measured using a differential scanning calorimeter (TA instrument Q100) and the experimental solubility was determined by the gravimetric method. The experimental solubility data were correlated by the equation for solubility of a solid in a liquid, and the activity coefficients were estimated by a non-random two liquid (NRTL), universal quasi-chemical (UNIQUAC), and Wilson models.</description><subject>(Solid + liquid) equilibrium</subject><subject>Alcohols</subject><subject>Climbazole</subject><subject>Correlation</subject><subject>Ethanol</subject><subject>Ethyl alcohol</subject><subject>Liquids</subject><subject>Mathematical analysis</subject><subject>Melting</subject><subject>Scanning</subject><subject>Solubility</subject><issn>0021-9614</issn><issn>1096-3626</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLxDAQhYMouK7-AG89emmdadp0iydZXBUWPKjnkKYTTMlu1qRdWH-9Wdaz8GDm8L1h3mPsFqFAQHE_FIMeixKwKiAJ8YzNEFqRc1GKczYDKDFvBVaX7CrGAQBa3sKMrd69mzrr7HjIvMm0s5tO_XhHmd1mexWsn2KmnPZf3qVlzHprDAXajtlImx0FNU6B4jW7MMpFuvmbc_a5evpYvuTrt-fX5eM615zDmDe44KIz3KBpTM9R0YJ0p3XdkOJdpaHtTYk1lDXyRVuVXNVNpQQJI-peCeBzdne6uwv-e6I4yo2NmpxTW0qfSlwAVGVbV1VC8YTq4GMMZOQu2I0KB4kgj53JQabO5LEzCUmIyfNw8lDKsLcUZNSWtpp6Gyixvbf_uH8BRE90-A</recordid><startdate>20141001</startdate><enddate>20141001</enddate><creator>Kim, Hakmin</creator><creator>Lim, Junhyuk</creator><creator>Hong, Jung Hyun</creator><creator>Kim, Ah Reum</creator><creator>Shin, Moon Sam</creator><creator>Kim, Hwayong</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20141001</creationdate><title>Solubility of climbazole in various alcohols at different temperatures</title><author>Kim, Hakmin ; Lim, Junhyuk ; Hong, Jung Hyun ; Kim, Ah Reum ; Shin, Moon Sam ; Kim, Hwayong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c330t-71836bf3f1f7fd31ae8ecbcc57ea3b4c09df2150251389423a574a6e6f65da603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>(Solid + liquid) equilibrium</topic><topic>Alcohols</topic><topic>Climbazole</topic><topic>Correlation</topic><topic>Ethanol</topic><topic>Ethyl alcohol</topic><topic>Liquids</topic><topic>Mathematical analysis</topic><topic>Melting</topic><topic>Scanning</topic><topic>Solubility</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Hakmin</creatorcontrib><creatorcontrib>Lim, Junhyuk</creatorcontrib><creatorcontrib>Hong, Jung Hyun</creatorcontrib><creatorcontrib>Kim, Ah Reum</creatorcontrib><creatorcontrib>Shin, Moon Sam</creatorcontrib><creatorcontrib>Kim, Hwayong</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>The Journal of chemical thermodynamics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Hakmin</au><au>Lim, Junhyuk</au><au>Hong, Jung Hyun</au><au>Kim, Ah Reum</au><au>Shin, Moon Sam</au><au>Kim, Hwayong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solubility of climbazole in various alcohols at different temperatures</atitle><jtitle>The Journal of chemical thermodynamics</jtitle><date>2014-10-01</date><risdate>2014</risdate><volume>77</volume><spage>1</spage><epage>6</epage><pages>1-6</pages><issn>0021-9614</issn><eissn>1096-3626</eissn><abstract>•Solubility data of climbazole in various alcohols were measured.•The experimental data were correlated with NRTL, UNIQUAC and Wilson models.•The data are fit well with all three models for the six pure alcohols studied.
(Solid+liquid) equilibria for climbazole in various alcohols (ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-heptanol) were investigated. The solubility data for climbazole in pure alcohols were obtained at temperatures ranging from (278.15 to 318.15)K. The melting temperature and fusion enthalpy of climbazole were measured using a differential scanning calorimeter (TA instrument Q100) and the experimental solubility was determined by the gravimetric method. The experimental solubility data were correlated by the equation for solubility of a solid in a liquid, and the activity coefficients were estimated by a non-random two liquid (NRTL), universal quasi-chemical (UNIQUAC), and Wilson models.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.jct.2014.04.011</doi><tpages>6</tpages></addata></record> |
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| source | Elsevier ScienceDirect Journals Complete - AutoHoldings |
| subjects | (Solid + liquid) equilibrium Alcohols Climbazole Correlation Ethanol Ethyl alcohol Liquids Mathematical analysis Melting Scanning Solubility |
| title | Solubility of climbazole in various alcohols at different temperatures |
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