Study of organic compounds–water interactions by partition in aqueous two-phase systems

•Partition coefficients of fourteen organic compounds were determined in 10–20 ATPS.•Solute-specific coefficients for the compounds examined were determined.•The partition behavior for the compounds is affected by dipole–ion interactions.•Partition ratios values for the compounds can be predicted.•T...

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Veröffentlicht in:	Journal of Chromatography A 2013-12, Vol.1322, p.97-104
Hauptverfasser:	Madeira, Pedro P., Bessa, Ana, Teixeira, Miguel A., Álvares-Ribeiro, Luís, Aires-Barros, M. Raquel, Rodrigues, Alírio E., Zaslavsky, Boris Y.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aqueous environments Aqueous two-phase partitioning Aroma and flavouring agent industries Binary systems (materials) Biological and medical sciences Buffers Food industries Fundamental and applied biological sciences. Psychology Hydrogen Bonding Hydrogen bonds Hydrogen-Ion Concentration Ion–dipole interactions Molecular Structure Odor threshold Organic Chemicals - chemistry Organic compounds Organic compounds–water interactions Partitions Polymers - chemistry Quantitative Structure-Activity Relationship Solute-specific coefficients Solvents Solvents - chemistry Static Electricity Water - chemistry
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