Bidentate forms of β-triketimines: syntheses, characterization and outstanding performance of enamine-diimine cobalt complexes in isoprene polymerization

New cationic enamine-β-diimine cobalt complex [LCoBr·THF][BArF] ( I ) and its neutral analogue [LCoBr 2 ] ( II ) where L = [(2,4,6-Me 3 -C 6 H 2 )NHCMe&z.dbd;C{CMe&z.dbd;( N -2,4,6-Me 3 (C 6 H 2 ))} 2 ] and BArF − = [{3,5-(CF 3 ) 2 C 6 H 3 } 4 B] − , were synthesised and then characterized b...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2016-06, Vol.45 (25), p.1435-1446
Hauptverfasser:	Alnajrani, Mohammed N, Mair, Francis S
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Cobalt Diffraction Isoprene Organoaluminium compounds Polyisoprenes Polymerization
Online-Zugang:	Volltext
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