Synthesis of a mononuclear, non-square-planar chromium(ii) bis(alkoxide) complex and its reactivity toward organic carbonyls and CO2

In this paper, we report the synthesis and reactivity of a rare mononuclear chromium(ii) bis(alkoxide) complex, Cr(OR')2(THF)2, that is supported by a new bulky alkoxide ligand (OR' = di-t-butyl-(3,5-diphenylphenyl)methoxide). The complex is prepared by protonolysis of square-planar Cr(N(S...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2016-06, Vol.45 (24), p.9794-9804
Hauptverfasser: Yousif, Maryam, Cabelof, Alyssa C, Martin, Philip D, Lord, Richard L, Groysman, Stanislav
Format: Artikel
Sprache:eng
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