Synthesis and Comprehensive Structural and Chiroptical Characterization of Enones Derived from (−)-α-Santonin by Experiment and Theory

The aim of the present work is to explain the causes of the observed deviations from sector and helicity rules to determine the absolute configuration of optically active α,β-unsaturated ketones by means of electronic circular dichroism (ECD). To this end, a series of model compounds with a common d...

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Veröffentlicht in:	Journal of organic chemistry 2016-06, Vol.81 (11), p.4588-4600
Hauptverfasser:	Masnyk, Marek, Butkiewicz, Aleksandra, Górecki, Marcin, Luboradzki, Roman, Bannwarth, Christoph, Grimme, Stefan, Frelek, Jadwiga
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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