tert-Butyl Nitrite: Organic Redox Cocatalyst for Aerobic Aldehyde-Selective Wacker–Tsuji Oxidation

An aldehyde-selective aerobic Wacker–Tsuji oxidation is developed. Using tert-butyl nitrite as a simple organic redox cocatalyst instead of copper or silver salts, a variety of aldehydes were achieved as major products in up to 30/1 regioselectivity as well as good to high yields at room temperature...

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Veröffentlicht in:	Organic letters 2016-06, Vol.18 (11), p.2700-2703
Hauptverfasser:	Ning, Xiao-Shan, Wang, Mei-Mei, Yao, Chuan-Zhi, Chen, Xian-Min, Kang, Yan-Biao
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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