Nickel-Catalyzed Stereoselective Dicarbofunctionalization of Alkynes

A nickel‐catalyzed three‐component reaction involving terminal alkynes, boronic acids, and alkyl halides is presented herein. Trisubstituted alkenes can be obtained in a highly regio‐ and stereocontrolled manner by the simultaneous addition of both aryl and alkyl groups across the triple bond in a r...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-06, Vol.55 (24), p.6938-6941
Hauptverfasser:	Li, Zhaodong, García-Domínguez, Andrés, Nevado, Cristina
Format:	Artikel
Sprache:	eng
Schlagworte:	alkyl halides alkynes boron nickel radicals
Online-Zugang:	Volltext
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