Active and Durable Hydrogen Evolution Reaction Catalyst Derived from Pd-Doped Metal–Organic Frameworks

Active and Durable Hydrogen Evolution Reaction Catalyst Derived from Pd-Doped Metal–Organic Frameworks

The water electrolysis is of critical importance for sustainable hydrogen production. In this work, a highly efficient and stable PdCo alloy catalyst (PdCo@CN) was synthesized by direct annealing of Pd-doped metal–organic frameworks (MOFs) under N2 atmosphere. In 0.5 M H2SO4 solution, PdCo@CN displa...

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Veröffentlicht in:ACS applied materials & interfaces 2016-06, Vol.8 (21), p.13378-13383
Hauptverfasser: Chen, Jitang, Xia, Guoliang, Jiang, Peng, Yang, Yang, Li, Ren, Shi, Ruohong, Su, Jianwei, Chen, Qianwang
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container_issue 21
container_start_page 13378
container_title ACS applied materials & interfaces
container_volume 8
creator Chen, Jitang
Xia, Guoliang
Jiang, Peng
Yang, Yang
Li, Ren
Shi, Ruohong
Su, Jianwei
Chen, Qianwang
description The water electrolysis is of critical importance for sustainable hydrogen production. In this work, a highly efficient and stable PdCo alloy catalyst (PdCo@CN) was synthesized by direct annealing of Pd-doped metal–organic frameworks (MOFs) under N2 atmosphere. In 0.5 M H2SO4 solution, PdCo@CN displays remarkable electrocatalytic performance with overpotential of 80 mV, a Tafel slope of 31 mV dec–1, and excellent stability of 10 000 cycles. Our studies reveal that noble metal doped MOFs are ideal precursors for preparing highly active alloy electrocatalysts with low content of noble metal.
doi_str_mv 10.1021/acsami.6b01266
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title Active and Durable Hydrogen Evolution Reaction Catalyst Derived from Pd-Doped Metal–Organic Frameworks
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