A Biomimetic Mechanism for the Copper-Catalyzed Aerobic Oxygenation of 4-tert-Butylphenol

Controlling product selectivity during the catalytic aerobic oxidation of phenols remains a significant challenge that hinders reaction development. This work provides a mechanistic picture of a Cu-catalyzed, aerobic functionalization of phenols that is selective for phenoxy-coupled ortho-quinones....

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Veröffentlicht in:	Inorganic chemistry 2015-09, Vol.54 (17), p.8665-8672
Hauptverfasser:	Askari, Mohammad S, Esguerra, Kenneth Virgel N, Lumb, Jean-Philip, Ottenwaelder, Xavier
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetic Materials - chemistry Catalysis Catalysts Copper Copper - chemistry Enzymes Molecular Structure Monophenol Monooxygenase - metabolism Oxidants Oxidation Oxygen - chemistry Oxygenation Phenols Phenols - chemistry Self assembly
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