Octaiodoporphyrin

Interaction of 3,4-diiodopyrrole with 4-trifluoromethylbenzaldeyde under carefully optimized, Lindsey-type conditions at −10 °C has led to the synthesis of the first β-octaiodoporphyrin, H2[I8TpCF3PP]. The free ligand readily yielded Ni, Cu, and Zn complexes, which all proved amenable to single-crys...

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Veröffentlicht in:	Inorganic chemistry 2015-12, Vol.54 (23), p.11493-11497
Hauptverfasser:	Thomassen, Ivar K, Vazquez-Lima, Hugo, Gagnon, Kevin J, Ghosh, Abhik
Format:	Artikel
Sprache:	eng
Schlagworte:	Ligands Nickel Polypropylenes Porphyrins Structural analysis Synthesis X-rays Zinc
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container_title	Inorganic chemistry
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creator	Thomassen, Ivar K Vazquez-Lima, Hugo Gagnon, Kevin J Ghosh, Abhik
description	Interaction of 3,4-diiodopyrrole with 4-trifluoromethylbenzaldeyde under carefully optimized, Lindsey-type conditions at −10 °C has led to the synthesis of the first β-octaiodoporphyrin, H2[I8TpCF3PP]. The free ligand readily yielded Ni, Cu, and Zn complexes, which all proved amenable to single-crystal X-ray structure analyses. The zinc complex Zn[I8TpCF3PP] exhibits the most saddled porphyrin core for any simple porphyrin known to date and a dramatically red-shifted optical spectrum with a Soret maximum at 495 nm.
doi_str_mv	10.1021/acs.inorgchem.5b02127
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The free ligand readily yielded Ni, Cu, and Zn complexes, which all proved amenable to single-crystal X-ray structure analyses. 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Chem</addtitle><description>Interaction of 3,4-diiodopyrrole with 4-trifluoromethylbenzaldeyde under carefully optimized, Lindsey-type conditions at −10 °C has led to the synthesis of the first β-octaiodoporphyrin, H2[I8TpCF3PP]. The free ligand readily yielded Ni, Cu, and Zn complexes, which all proved amenable to single-crystal X-ray structure analyses. 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subjects	Ligands Nickel Polypropylenes Porphyrins Structural analysis Synthesis X-rays Zinc
title	Octaiodoporphyrin
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