A New Design Strategy to Access Zwitterionic Metal–Organic Frameworks from Anionic Viologen Derivates

Two isostructural microporous zwitterionic metal–organic frameworks (ZW MOFs), {[M(bdcbpy)(OH2)4]·4H2O} n with M = Mn (1) and Ni (2), were synthesized by the rational design of the flexible anionic viologen derivate, 1,1′-bis(3,5-dicarboxybenzyl)-4,4′-bipyridinium dibromide dihydrate solvate (H4bdcb...

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Veröffentlicht in:	Inorganic chemistry 2015-02, Vol.54 (4), p.1756-1764
Hauptverfasser:	Aulakh, Darpandeep, Varghese, Juby R, Wriedt, Mario
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates Design analysis Design engineering Metal-organic frameworks Metalorganic compounds Porosity Self assembly Surface chemistry Three dimensional
Online-Zugang:	Volltext
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