Influence of electron beam irradiation on the structural, electrical and thermal properties of Gd0.5Sr0.5MnO3 and Dy0.5Sr0.5MnO3 manganites

•Pristine and irradiated samples follow small polaron hopping model in high temperature range.•Reduction in volume is seen via electron beam irradiation.•High temperature thermoelectric power data follows small polaron hopping model.•Electron beam irradiation enhances thermoelectric power for Gd0.5S...

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Veröffentlicht in:Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms Beam interactions with materials and atoms, 2016-01, Vol.366, p.188-197
Hauptverfasser: Nagaraja, B.S., Rao, Ashok, Babu, P.D., Sanjeev, Ganesh, Okram, G.S.
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Sprache:eng
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Zusammenfassung:•Pristine and irradiated samples follow small polaron hopping model in high temperature range.•Reduction in volume is seen via electron beam irradiation.•High temperature thermoelectric power data follows small polaron hopping model.•Electron beam irradiation enhances thermoelectric power for Gd0.5Sr0.5MnO3 compounds. We present systematic studies on the effect of electron beam irradiation on structural, electrical and thermal properties of Gd0.5Sr0.5MnO3 and Dy0.5Sr0.5MnO3 manganites. The XRD patterns and Rietveld analysis show that the samples remain single phased even after they undergo electron beam irradiation. Both the series of the samples Gd0.5Sr0.5MnO3 and Dy0.5Sr0.5MnO3 show insulating trends in their temperature dependent electrical resistivity, ρ(T) behavior. The resistivity data for both the series of samples (pristine as well as irradiated) indicate that the small polaron hopping model is valid in high temperature region; on contrary, variable range hopping model governs the low temperature regime. Magnetic studies demonstrate that the Neel temperatures of pristine and irradiated samples of Gd0.5Sr0.5MnO3 and Dy0.5Sr0.5MnO3 do not change appreciably when they are subjected to irradiation. Thermo-electrical power is observed to increase with irradiation in Gd0.5Sr0.5MnO3 samples, whereas for Dy0.5Sr0.5MnO3 samples a decrease in thermo-electric power is seen when the samples are irradiated.
ISSN:0168-583X
1872-9584
DOI:10.1016/j.nimb.2015.11.009