Green Synthesis of Polyimides and Their CNT Based Nanohybrid Shish- Kebabs through Reaction-induced Crystallization of Nylon-salt-type Monomers in Glycerol
A green approach to the synthesis and morphological control of high performance polyimides and their nanohybrid shish-kebabs in glycerol through reaction-induced crystallization of nylon-salt-type monomers was reported. Crystalline polyimide nanoplates can be observed by direct polycondensation of p...
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| Veröffentlicht in: | Chinese journal of polymer science 2014-08, Vol.32 (8), p.1052-1059 |
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| container_title | Chinese journal of polymer science |
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| creator | Li, Xiao-juan Chen, Lu Huang, Wei Li, Xiang Zhang, Chao-liang Liu, Xi-kui |
| description | A green approach to the synthesis and morphological control of high performance polyimides and their nanohybrid shish-kebabs in glycerol through reaction-induced crystallization of nylon-salt-type monomers was reported. Crystalline polyimide nanoplates can be observed by direct polycondensation of pyromellitic acid with various kinds of aliphatic or aromatic diamines. With the existence of carbon nanotuhes, the polyimides can be successfully decorated on the surface of CNTs through a reaction-induced hetero-epitaxial crystallization process, and resulted in novel polyimide/CNT nanohybrid shish-kebabs （NHSKs） structures. The morphologies of the NHSKs can be fine-tuned through changing the concentration of monomers or the reaction temperature, especially through the introduction of dynamic imine chemistry, the formation process of NHSKs can be attributed to a soft epitaxy mechanism. Thus a green approach for the synthesis of high performance polyimides and their CNT based nanohybrid structures was explored, which should be of great value for their applications in high performance reinforced nanocomposites. |
| doi_str_mv | 10.1007/s10118-014-1480-3 |
| format | Article |
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Crystalline polyimide nanoplates can be observed by direct polycondensation of pyromellitic acid with various kinds of aliphatic or aromatic diamines. With the existence of carbon nanotuhes, the polyimides can be successfully decorated on the surface of CNTs through a reaction-induced hetero-epitaxial crystallization process, and resulted in novel polyimide/CNT nanohybrid shish-kebabs （NHSKs） structures. The morphologies of the NHSKs can be fine-tuned through changing the concentration of monomers or the reaction temperature, especially through the introduction of dynamic imine chemistry, the formation process of NHSKs can be attributed to a soft epitaxy mechanism. Thus a green approach for the synthesis of high performance polyimides and their CNT based nanohybrid structures was explored, which should be of great value for their applications in high performance reinforced nanocomposites.</description><identifier>ISSN: 0256-7679</identifier><identifier>EISSN: 1439-6203</identifier><identifier>DOI: 10.1007/s10118-014-1480-3</identifier><language>eng</language><publisher>Heidelberg: Chinese Chemical Society and Institute of Chemistry, CAS</publisher><subject>Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; CNT ; Condensed Matter Physics ; Crystal structure ; Crystallization ; Glycerols ; Industrial Chemistry/Chemical Engineering ; Monomers ; Nanocomposites ; Nanostructure ; Polyimide resins ; Polymer Sciences ; Synthesis ; 单体 ; 反应温度 ; 烤羊肉串 ; 纳米杂化 ; 绿色合成 ; 聚酰亚胺 ; 诱导结晶</subject><ispartof>Chinese journal of polymer science, 2014-08, Vol.32 (8), p.1052-1059</ispartof><rights>Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag Berlin Heidelberg 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c348t-8947c968e8b8257264039b1c25eb62619cc2e1c3ad77bdaa4fa1420df204c74d3</citedby><cites>FETCH-LOGICAL-c348t-8947c968e8b8257264039b1c25eb62619cc2e1c3ad77bdaa4fa1420df204c74d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/86788X/86788X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10118-014-1480-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10118-014-1480-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Li, Xiao-juan</creatorcontrib><creatorcontrib>Chen, Lu</creatorcontrib><creatorcontrib>Huang, Wei</creatorcontrib><creatorcontrib>Li, Xiang</creatorcontrib><creatorcontrib>Zhang, Chao-liang</creatorcontrib><creatorcontrib>Liu, Xi-kui</creatorcontrib><title>Green Synthesis of Polyimides and Their CNT Based Nanohybrid Shish- Kebabs through Reaction-induced Crystallization of Nylon-salt-type Monomers in Glycerol</title><title>Chinese journal of polymer science</title><addtitle>Chin J Polym Sci</addtitle><addtitle>Chinese Journal of Polymer Science</addtitle><description>A green approach to the synthesis and morphological control of high performance polyimides and their nanohybrid shish-kebabs in glycerol through reaction-induced crystallization of nylon-salt-type monomers was reported. Crystalline polyimide nanoplates can be observed by direct polycondensation of pyromellitic acid with various kinds of aliphatic or aromatic diamines. With the existence of carbon nanotuhes, the polyimides can be successfully decorated on the surface of CNTs through a reaction-induced hetero-epitaxial crystallization process, and resulted in novel polyimide/CNT nanohybrid shish-kebabs （NHSKs） structures. The morphologies of the NHSKs can be fine-tuned through changing the concentration of monomers or the reaction temperature, especially through the introduction of dynamic imine chemistry, the formation process of NHSKs can be attributed to a soft epitaxy mechanism. Thus a green approach for the synthesis of high performance polyimides and their CNT based nanohybrid structures was explored, which should be of great value for their applications in high performance reinforced nanocomposites.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>CNT</subject><subject>Condensed Matter Physics</subject><subject>Crystal structure</subject><subject>Crystallization</subject><subject>Glycerols</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Monomers</subject><subject>Nanocomposites</subject><subject>Nanostructure</subject><subject>Polyimide resins</subject><subject>Polymer Sciences</subject><subject>Synthesis</subject><subject>单体</subject><subject>反应温度</subject><subject>烤羊肉串</subject><subject>纳米杂化</subject><subject>绿色合成</subject><subject>聚酰亚胺</subject><subject>诱导结晶</subject><issn>0256-7679</issn><issn>1439-6203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kU2P0zAQhiMEEmXhB3CzOHEx66_YyREqtqBdCmLL2XKcaeOVa3c9ySH8Ff4sqbriyGmk0fvMq9FTVW85-8AZM9fIGecNZVxRrhpG5bNqxZVsqRZMPq9WTNSaGm3al9UrxAfGtDK1WVV_NgUgkfs5jQNgQJL35EeOcziGHpC41JPdAKGQ9XZHPjmEnmxdysPcldCT-yHgQMktdK5DMg4lT4eB_ATnx5ATDamf_EKsy4yjizH8duf9uWM7xyWALo50nE9AvuWUj1CQhEQ2cfZQcnxdvdi7iPDmaV5Vv24-79Zf6N33zdf1xzvqpWpG2rTK-FY30HSNqI3Qism2417U0Gmheeu9AO6l643peufU3nElWL8XTHmjenlVvb_cPZX8OAGO9hjQQ4wuQZ7QctNKYRiv9RLll6gvGbHA3p5KOLoyW87sWYS9iLCLCHsWYeXCiAuDSzYdoNiHPJW0fPRf6N1T0ZDT4XHh_jVpzReRSjXyL4t4mM4</recordid><startdate>20140801</startdate><enddate>20140801</enddate><creator>Li, Xiao-juan</creator><creator>Chen, Lu</creator><creator>Huang, Wei</creator><creator>Li, Xiang</creator><creator>Zhang, Chao-liang</creator><creator>Liu, Xi-kui</creator><general>Chinese Chemical Society and Institute of Chemistry, CAS</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20140801</creationdate><title>Green Synthesis of Polyimides and Their CNT Based Nanohybrid Shish- Kebabs through Reaction-induced Crystallization of Nylon-salt-type Monomers in Glycerol</title><author>Li, Xiao-juan ; Chen, Lu ; Huang, Wei ; Li, Xiang ; Zhang, Chao-liang ; Liu, Xi-kui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c348t-8947c968e8b8257264039b1c25eb62619cc2e1c3ad77bdaa4fa1420df204c74d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>CNT</topic><topic>Condensed Matter Physics</topic><topic>Crystal structure</topic><topic>Crystallization</topic><topic>Glycerols</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Monomers</topic><topic>Nanocomposites</topic><topic>Nanostructure</topic><topic>Polyimide resins</topic><topic>Polymer Sciences</topic><topic>Synthesis</topic><topic>单体</topic><topic>反应温度</topic><topic>烤羊肉串</topic><topic>纳米杂化</topic><topic>绿色合成</topic><topic>聚酰亚胺</topic><topic>诱导结晶</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Xiao-juan</creatorcontrib><creatorcontrib>Chen, Lu</creatorcontrib><creatorcontrib>Huang, Wei</creatorcontrib><creatorcontrib>Li, Xiang</creatorcontrib><creatorcontrib>Zhang, Chao-liang</creatorcontrib><creatorcontrib>Liu, Xi-kui</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chinese journal of polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Xiao-juan</au><au>Chen, Lu</au><au>Huang, Wei</au><au>Li, Xiang</au><au>Zhang, Chao-liang</au><au>Liu, Xi-kui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Green Synthesis of Polyimides and Their CNT Based Nanohybrid Shish- Kebabs through Reaction-induced Crystallization of Nylon-salt-type Monomers in Glycerol</atitle><jtitle>Chinese journal of polymer science</jtitle><stitle>Chin J Polym Sci</stitle><addtitle>Chinese Journal of Polymer Science</addtitle><date>2014-08-01</date><risdate>2014</risdate><volume>32</volume><issue>8</issue><spage>1052</spage><epage>1059</epage><pages>1052-1059</pages><issn>0256-7679</issn><eissn>1439-6203</eissn><abstract>A green approach to the synthesis and morphological control of high performance polyimides and their nanohybrid shish-kebabs in glycerol through reaction-induced crystallization of nylon-salt-type monomers was reported. Crystalline polyimide nanoplates can be observed by direct polycondensation of pyromellitic acid with various kinds of aliphatic or aromatic diamines. With the existence of carbon nanotuhes, the polyimides can be successfully decorated on the surface of CNTs through a reaction-induced hetero-epitaxial crystallization process, and resulted in novel polyimide/CNT nanohybrid shish-kebabs （NHSKs） structures. The morphologies of the NHSKs can be fine-tuned through changing the concentration of monomers or the reaction temperature, especially through the introduction of dynamic imine chemistry, the formation process of NHSKs can be attributed to a soft epitaxy mechanism. Thus a green approach for the synthesis of high performance polyimides and their CNT based nanohybrid structures was explored, which should be of great value for their applications in high performance reinforced nanocomposites.</abstract><cop>Heidelberg</cop><pub>Chinese Chemical Society and Institute of Chemistry, CAS</pub><doi>10.1007/s10118-014-1480-3</doi><tpages>8</tpages></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science CNT Condensed Matter Physics Crystal structure Crystallization Glycerols Industrial Chemistry/Chemical Engineering Monomers Nanocomposites Nanostructure Polyimide resins Polymer Sciences Synthesis 单体 反应温度 烤羊肉串 纳米杂化 绿色合成 聚酰亚胺 诱导结晶 |
| title | Green Synthesis of Polyimides and Their CNT Based Nanohybrid Shish- Kebabs through Reaction-induced Crystallization of Nylon-salt-type Monomers in Glycerol |
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