Grain rotation and lattice deformation during photoinduced chemical reactions revealed by in situ X-ray nanodiffraction
An in situ X-ray nanodiffraction technique allows for the real-time study of the photoinduced chemical reaction to produce Ag from AgBr, and can spatially resolve structural changes at the submicrometre scale with a time resolution of 5 ms. In situ X-ray diffraction (XRD) and transmission electron m...
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| Veröffentlicht in: | Nature materials 2015-07, Vol.14 (7), p.691-695 |
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| creator | Huang, Zhifeng Bartels, Matthias Xu, Rui Osterhoff, Markus Kalbfleisch, Sebastian Sprung, Michael Suzuki, Akihiro Takahashi, Yukio Blanton, Thomas N. Salditt, Tim Miao, Jianwei |
| description | An
in situ
X-ray nanodiffraction technique allows for the real-time study of the photoinduced chemical reaction to produce Ag from AgBr, and can spatially resolve structural changes at the submicrometre scale with a time resolution of 5 ms.
In situ
X-ray diffraction (XRD) and transmission electron microscopy (TEM) have been used to investigate many physical science phenomena, ranging from phase transitions, chemical reactions and crystal growth to grain boundary dynamics
1
,
2
,
3
,
4
,
5
,
6
. A major limitation of
in situ
XRD and TEM is a compromise that has to be made between spatial and temporal resolution
1
,
2
,
3
,
4
,
5
,
6
. Here, we report the development of
in situ
X-ray nanodiffraction to measure high-resolution diffraction patterns from single grains with up to 5 ms temporal resolution. We observed, for the first time, grain rotation and lattice deformation in chemical reactions induced by X-ray photons: Br
−
+
hv
→ Br + e
−
and e
−
+ Ag
+
→ Ag
0
. The grain rotation and lattice deformation associated with the chemical reactions were quantified to be as fast as 3.25 rad s
−1
and as large as 0.5 Å, respectively. The ability to measure high-resolution diffraction patterns from individual grains with a temporal resolution of several milliseconds is expected to find broad applications in materials science, physics, chemistry and nanoscience. |
| doi_str_mv | 10.1038/nmat4311 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1793261235</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1793261235</sourcerecordid><originalsourceid>FETCH-LOGICAL-c551t-46026ce537ccb9f32fa1a5b7358ee6613d2816aa9c71ab56169ec1a4e24e0b5b3</originalsourceid><addsrcrecordid>eNqFkcFu1DAQhi0EoqUg9QkqS1zoYanHjp3kWFW0IFXiAlJv0cSZtK4Se2s7iH0bnoUnw6vdUtQLJ488n76Z0c_YMYiPIFRz5mfMlQJ4wQ6hqs2qMka83NcAUh6wNyndCyFBa_OaHUgjtKqNOGQ_ryI6z2PImF3wHP3AJ8zZWeIDjSHOu_9hic7f8vVdyMH5YbE0cHtHs7M48Uhot1Qq1Q_CqfT6DXf-96_k8sJvVhE33KMPgxvHuGPfslcjTone7d8j9v3y07eLz6vrr1dfLs6vV1ZryOUSIY2lsq21fTsqOSKg7mulGyJjQA2yAYPY2hqw1wZMSxawIlmR6HWvjtiHnXcdw8NCKXezS5amCT2FJXVQt0oakEr_HzUtCFDGtAV9_wy9D0v05ZAiNLVoGlG3T0IbQ0qRxm4d3Yxx04HotsF1j8EV9GQvXPqZhr_gY1IFON0Bab1NguI_E5_L_gDWAKNq</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1767088079</pqid></control><display><type>article</type><title>Grain rotation and lattice deformation during photoinduced chemical reactions revealed by in situ X-ray nanodiffraction</title><source>SpringerLink Journals</source><source>Nature Journals Online</source><creator>Huang, Zhifeng ; Bartels, Matthias ; Xu, Rui ; Osterhoff, Markus ; Kalbfleisch, Sebastian ; Sprung, Michael ; Suzuki, Akihiro ; Takahashi, Yukio ; Blanton, Thomas N. ; Salditt, Tim ; Miao, Jianwei</creator><creatorcontrib>Huang, Zhifeng ; Bartels, Matthias ; Xu, Rui ; Osterhoff, Markus ; Kalbfleisch, Sebastian ; Sprung, Michael ; Suzuki, Akihiro ; Takahashi, Yukio ; Blanton, Thomas N. ; Salditt, Tim ; Miao, Jianwei</creatorcontrib><description>An
in situ
X-ray nanodiffraction technique allows for the real-time study of the photoinduced chemical reaction to produce Ag from AgBr, and can spatially resolve structural changes at the submicrometre scale with a time resolution of 5 ms.
In situ
X-ray diffraction (XRD) and transmission electron microscopy (TEM) have been used to investigate many physical science phenomena, ranging from phase transitions, chemical reactions and crystal growth to grain boundary dynamics
1
,
2
,
3
,
4
,
5
,
6
. A major limitation of
in situ
XRD and TEM is a compromise that has to be made between spatial and temporal resolution
1
,
2
,
3
,
4
,
5
,
6
. Here, we report the development of
in situ
X-ray nanodiffraction to measure high-resolution diffraction patterns from single grains with up to 5 ms temporal resolution. We observed, for the first time, grain rotation and lattice deformation in chemical reactions induced by X-ray photons: Br
−
+
hv
→ Br + e
−
and e
−
+ Ag
+
→ Ag
0
. The grain rotation and lattice deformation associated with the chemical reactions were quantified to be as fast as 3.25 rad s
−1
and as large as 0.5 Å, respectively. The ability to measure high-resolution diffraction patterns from individual grains with a temporal resolution of several milliseconds is expected to find broad applications in materials science, physics, chemistry and nanoscience.</description><identifier>ISSN: 1476-1122</identifier><identifier>EISSN: 1476-4660</identifier><identifier>DOI: 10.1038/nmat4311</identifier><identifier>PMID: 26053760</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/301/930/12 ; 639/925/357 ; Biomaterials ; Chemical reactions ; Condensed Matter Physics ; Crystal growth ; Deformation ; Diffraction ; Diffraction patterns ; Grains ; Lattices ; letter ; Materials Science ; Nanomaterials ; Nanotechnology ; Optical and Electronic Materials ; Physics ; Temporal resolution ; Transmission electron microscopy ; X-ray diffraction ; X-rays</subject><ispartof>Nature materials, 2015-07, Vol.14 (7), p.691-695</ispartof><rights>Springer Nature Limited 2014</rights><rights>Copyright Nature Publishing Group Jul 2015</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c551t-46026ce537ccb9f32fa1a5b7358ee6613d2816aa9c71ab56169ec1a4e24e0b5b3</citedby><cites>FETCH-LOGICAL-c551t-46026ce537ccb9f32fa1a5b7358ee6613d2816aa9c71ab56169ec1a4e24e0b5b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1038/nmat4311$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1038/nmat4311$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26053760$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Huang, Zhifeng</creatorcontrib><creatorcontrib>Bartels, Matthias</creatorcontrib><creatorcontrib>Xu, Rui</creatorcontrib><creatorcontrib>Osterhoff, Markus</creatorcontrib><creatorcontrib>Kalbfleisch, Sebastian</creatorcontrib><creatorcontrib>Sprung, Michael</creatorcontrib><creatorcontrib>Suzuki, Akihiro</creatorcontrib><creatorcontrib>Takahashi, Yukio</creatorcontrib><creatorcontrib>Blanton, Thomas N.</creatorcontrib><creatorcontrib>Salditt, Tim</creatorcontrib><creatorcontrib>Miao, Jianwei</creatorcontrib><title>Grain rotation and lattice deformation during photoinduced chemical reactions revealed by in situ X-ray nanodiffraction</title><title>Nature materials</title><addtitle>Nature Mater</addtitle><addtitle>Nat Mater</addtitle><description>An
in situ
X-ray nanodiffraction technique allows for the real-time study of the photoinduced chemical reaction to produce Ag from AgBr, and can spatially resolve structural changes at the submicrometre scale with a time resolution of 5 ms.
In situ
X-ray diffraction (XRD) and transmission electron microscopy (TEM) have been used to investigate many physical science phenomena, ranging from phase transitions, chemical reactions and crystal growth to grain boundary dynamics
1
,
2
,
3
,
4
,
5
,
6
. A major limitation of
in situ
XRD and TEM is a compromise that has to be made between spatial and temporal resolution
1
,
2
,
3
,
4
,
5
,
6
. Here, we report the development of
in situ
X-ray nanodiffraction to measure high-resolution diffraction patterns from single grains with up to 5 ms temporal resolution. We observed, for the first time, grain rotation and lattice deformation in chemical reactions induced by X-ray photons: Br
−
+
hv
→ Br + e
−
and e
−
+ Ag
+
→ Ag
0
. The grain rotation and lattice deformation associated with the chemical reactions were quantified to be as fast as 3.25 rad s
−1
and as large as 0.5 Å, respectively. The ability to measure high-resolution diffraction patterns from individual grains with a temporal resolution of several milliseconds is expected to find broad applications in materials science, physics, chemistry and nanoscience.</description><subject>639/301/930/12</subject><subject>639/925/357</subject><subject>Biomaterials</subject><subject>Chemical reactions</subject><subject>Condensed Matter Physics</subject><subject>Crystal growth</subject><subject>Deformation</subject><subject>Diffraction</subject><subject>Diffraction patterns</subject><subject>Grains</subject><subject>Lattices</subject><subject>letter</subject><subject>Materials Science</subject><subject>Nanomaterials</subject><subject>Nanotechnology</subject><subject>Optical and Electronic Materials</subject><subject>Physics</subject><subject>Temporal resolution</subject><subject>Transmission electron microscopy</subject><subject>X-ray 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lattice deformation during photoinduced chemical reactions revealed by in situ X-ray nanodiffraction</atitle><jtitle>Nature materials</jtitle><stitle>Nature Mater</stitle><addtitle>Nat Mater</addtitle><date>2015-07-01</date><risdate>2015</risdate><volume>14</volume><issue>7</issue><spage>691</spage><epage>695</epage><pages>691-695</pages><issn>1476-1122</issn><eissn>1476-4660</eissn><abstract>An
in situ
X-ray nanodiffraction technique allows for the real-time study of the photoinduced chemical reaction to produce Ag from AgBr, and can spatially resolve structural changes at the submicrometre scale with a time resolution of 5 ms.
In situ
X-ray diffraction (XRD) and transmission electron microscopy (TEM) have been used to investigate many physical science phenomena, ranging from phase transitions, chemical reactions and crystal growth to grain boundary dynamics
1
,
2
,
3
,
4
,
5
,
6
. A major limitation of
in situ
XRD and TEM is a compromise that has to be made between spatial and temporal resolution
1
,
2
,
3
,
4
,
5
,
6
. Here, we report the development of
in situ
X-ray nanodiffraction to measure high-resolution diffraction patterns from single grains with up to 5 ms temporal resolution. We observed, for the first time, grain rotation and lattice deformation in chemical reactions induced by X-ray photons: Br
−
+
hv
→ Br + e
−
and e
−
+ Ag
+
→ Ag
0
. The grain rotation and lattice deformation associated with the chemical reactions were quantified to be as fast as 3.25 rad s
−1
and as large as 0.5 Å, respectively. The ability to measure high-resolution diffraction patterns from individual grains with a temporal resolution of several milliseconds is expected to find broad applications in materials science, physics, chemistry and nanoscience.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>26053760</pmid><doi>10.1038/nmat4311</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Nature materials, 2015-07, Vol.14 (7), p.691-695 |
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| language | eng |
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| source | SpringerLink Journals; Nature Journals Online |
| subjects | 639/301/930/12 639/925/357 Biomaterials Chemical reactions Condensed Matter Physics Crystal growth Deformation Diffraction Diffraction patterns Grains Lattices letter Materials Science Nanomaterials Nanotechnology Optical and Electronic Materials Physics Temporal resolution Transmission electron microscopy X-ray diffraction X-rays |
| title | Grain rotation and lattice deformation during photoinduced chemical reactions revealed by in situ X-ray nanodiffraction |
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