Self-assembly Behavior of Copolymers with Super Segregated Structure Containing Fluorinated Segments
Copolymers with super segregated structure of hydrophilic methoxy poly（ethylene glycol） （mPEG） and fluorophilic poly（1H,1H,2H,2H-perfluorodecyl acrylate） （PFA） were prepared. And just because of this super segregated structure which was resulted from the extremely strong incompatibility between the...
Gespeichert in:
| Veröffentlicht in: | Chinese journal of polymer science 2014-07, Vol.32 (7), p.817-817 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 817 |
|---|---|
| container_issue | 7 |
| container_start_page | 817 |
| container_title | Chinese journal of polymer science |
| container_volume | 32 |
| creator | Deng, Jin-ni Wang, Wen-bin Zheng, Zhao-hui Ding, Xiao-bin Peng, Yu-xing |
| description | Copolymers with super segregated structure of hydrophilic methoxy poly（ethylene glycol） （mPEG） and fluorophilic poly（1H,1H,2H,2H-perfluorodecyl acrylate） （PFA） were prepared. And just because of this super segregated structure which was resulted from the extremely strong incompatibility between the two blocks, several interesting self- assembly behaviors of the copolymers were displayed and studied under different conditions. Transmission electron microscope （TEM） showed that with the increase of PFA in the polymerization system, the incompatibility in this super segregated structure became stronger, and the self-assembly behavior changed from ball-like or rod-like to vesicles, and finally collapsed to sheet-like. The self-assembly behavior changed likewise when the initial concentration increased. And the interesting formation of these barrel-like and spindle-like vesicles was finally studied with different cooling speeds. It＇s finally found that with this super segregation structure, these new self-assembly morphology might be formed due to the extremely strong incompatibility between mPEG and PFA segments. |
| doi_str_mv | 10.1007/s10118-014-1476-z |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1793260529</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><cqvip_id>49825707</cqvip_id><sourcerecordid>1793260529</sourcerecordid><originalsourceid>FETCH-LOGICAL-c390t-781c986d18b45033e6602e6b7992045c56e8330549d23ec5302abfade1ad0a9a3</originalsourceid><addsrcrecordid>eNp9kLtOxDAQAC0EEsfjA-hCR2NY27Edl3DiJSFRHNSWL9nkghL7sBPQ8fUEBVFSbTOzqx1CzhhcMgB9lRgwVlBgOWW5VvRrjyxYLgxVHMQ-WQCXimqlzSE5SukNQOVa6gWpVtjV1KWE_brbZTe4cR9tiFmos2XYhm7XY0zZZztsstW4xZitsInYuAGrbDXEsRzGiBPqB9f61jfZXTeG2PoZwKZHP6QTclC7LuHp7zwmr3e3L8sH-vR8_7i8fqKlMDBQXbDSFKpixTqXIAQqBRzVWhvDIZelVFgIATI3FRdYSgHcrWtXIXMVOOPEMbmY925jeB8xDbZvU4ld5zyGMVmmjeAKJDcTyma0jCGliLXdxrZ3cWcZ2J-idi5qp6L2p6j9mhw-O2lifYPRvoUx-umjf6Xz30Ob4Jv3yfu7lJuCSw1afAP2aYXA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1793260529</pqid></control><display><type>article</type><title>Self-assembly Behavior of Copolymers with Super Segregated Structure Containing Fluorinated Segments</title><source>SpringerNature Journals</source><source>Alma/SFX Local Collection</source><creator>Deng, Jin-ni ; Wang, Wen-bin ; Zheng, Zhao-hui ; Ding, Xiao-bin ; Peng, Yu-xing</creator><creatorcontrib>Deng, Jin-ni ; Wang, Wen-bin ; Zheng, Zhao-hui ; Ding, Xiao-bin ; Peng, Yu-xing</creatorcontrib><description>Copolymers with super segregated structure of hydrophilic methoxy poly（ethylene glycol） （mPEG） and fluorophilic poly（1H,1H,2H,2H-perfluorodecyl acrylate） （PFA） were prepared. And just because of this super segregated structure which was resulted from the extremely strong incompatibility between the two blocks, several interesting self- assembly behaviors of the copolymers were displayed and studied under different conditions. Transmission electron microscope （TEM） showed that with the increase of PFA in the polymerization system, the incompatibility in this super segregated structure became stronger, and the self-assembly behavior changed from ball-like or rod-like to vesicles, and finally collapsed to sheet-like. The self-assembly behavior changed likewise when the initial concentration increased. And the interesting formation of these barrel-like and spindle-like vesicles was finally studied with different cooling speeds. It＇s finally found that with this super segregation structure, these new self-assembly morphology might be formed due to the extremely strong incompatibility between mPEG and PFA segments.</description><identifier>ISSN: 0256-7679</identifier><identifier>EISSN: 1439-6203</identifier><identifier>DOI: 10.1007/s10118-014-1476-z</identifier><language>eng</language><publisher>Heidelberg: Chinese Chemical Society and Institute of Chemistry, CAS</publisher><subject>Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Copolymers ; Incompatibility ; Industrial Chemistry/Chemical Engineering ; MPEG ; MPEG encoders ; PFA ; Polymer Sciences ; Segments ; Self assembly ; Vesicles ; Video compression ; 不相容性 ; 共聚物 ; 氟化 ; 种族 ; 自组装行为 ; 透射电子显微镜 ; 隔离结构</subject><ispartof>Chinese journal of polymer science, 2014-07, Vol.32 (7), p.817-817</ispartof><rights>Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag Berlin Heidelberg 2014</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c390t-781c986d18b45033e6602e6b7992045c56e8330549d23ec5302abfade1ad0a9a3</citedby><cites>FETCH-LOGICAL-c390t-781c986d18b45033e6602e6b7992045c56e8330549d23ec5302abfade1ad0a9a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/86788X/86788X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10118-014-1476-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10118-014-1476-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Deng, Jin-ni</creatorcontrib><creatorcontrib>Wang, Wen-bin</creatorcontrib><creatorcontrib>Zheng, Zhao-hui</creatorcontrib><creatorcontrib>Ding, Xiao-bin</creatorcontrib><creatorcontrib>Peng, Yu-xing</creatorcontrib><title>Self-assembly Behavior of Copolymers with Super Segregated Structure Containing Fluorinated Segments</title><title>Chinese journal of polymer science</title><addtitle>Chin J Polym Sci</addtitle><addtitle>Chinese Journal of Polymer Science</addtitle><description>Copolymers with super segregated structure of hydrophilic methoxy poly（ethylene glycol） （mPEG） and fluorophilic poly（1H,1H,2H,2H-perfluorodecyl acrylate） （PFA） were prepared. And just because of this super segregated structure which was resulted from the extremely strong incompatibility between the two blocks, several interesting self- assembly behaviors of the copolymers were displayed and studied under different conditions. Transmission electron microscope （TEM） showed that with the increase of PFA in the polymerization system, the incompatibility in this super segregated structure became stronger, and the self-assembly behavior changed from ball-like or rod-like to vesicles, and finally collapsed to sheet-like. The self-assembly behavior changed likewise when the initial concentration increased. And the interesting formation of these barrel-like and spindle-like vesicles was finally studied with different cooling speeds. It＇s finally found that with this super segregation structure, these new self-assembly morphology might be formed due to the extremely strong incompatibility between mPEG and PFA segments.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Copolymers</subject><subject>Incompatibility</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>MPEG</subject><subject>MPEG encoders</subject><subject>PFA</subject><subject>Polymer Sciences</subject><subject>Segments</subject><subject>Self assembly</subject><subject>Vesicles</subject><subject>Video compression</subject><subject>不相容性</subject><subject>共聚物</subject><subject>氟化</subject><subject>种族</subject><subject>自组装行为</subject><subject>透射电子显微镜</subject><subject>隔离结构</subject><issn>0256-7679</issn><issn>1439-6203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kLtOxDAQAC0EEsfjA-hCR2NY27Edl3DiJSFRHNSWL9nkghL7sBPQ8fUEBVFSbTOzqx1CzhhcMgB9lRgwVlBgOWW5VvRrjyxYLgxVHMQ-WQCXimqlzSE5SukNQOVa6gWpVtjV1KWE_brbZTe4cR9tiFmos2XYhm7XY0zZZztsstW4xZitsInYuAGrbDXEsRzGiBPqB9f61jfZXTeG2PoZwKZHP6QTclC7LuHp7zwmr3e3L8sH-vR8_7i8fqKlMDBQXbDSFKpixTqXIAQqBRzVWhvDIZelVFgIATI3FRdYSgHcrWtXIXMVOOPEMbmY925jeB8xDbZvU4ld5zyGMVmmjeAKJDcTyma0jCGliLXdxrZ3cWcZ2J-idi5qp6L2p6j9mhw-O2lifYPRvoUx-umjf6Xz30Ob4Jv3yfu7lJuCSw1afAP2aYXA</recordid><startdate>20140701</startdate><enddate>20140701</enddate><creator>Deng, Jin-ni</creator><creator>Wang, Wen-bin</creator><creator>Zheng, Zhao-hui</creator><creator>Ding, Xiao-bin</creator><creator>Peng, Yu-xing</creator><general>Chinese Chemical Society and Institute of Chemistry, CAS</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20140701</creationdate><title>Self-assembly Behavior of Copolymers with Super Segregated Structure Containing Fluorinated Segments</title><author>Deng, Jin-ni ; Wang, Wen-bin ; Zheng, Zhao-hui ; Ding, Xiao-bin ; Peng, Yu-xing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c390t-781c986d18b45033e6602e6b7992045c56e8330549d23ec5302abfade1ad0a9a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Copolymers</topic><topic>Incompatibility</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>MPEG</topic><topic>MPEG encoders</topic><topic>PFA</topic><topic>Polymer Sciences</topic><topic>Segments</topic><topic>Self assembly</topic><topic>Vesicles</topic><topic>Video compression</topic><topic>不相容性</topic><topic>共聚物</topic><topic>氟化</topic><topic>种族</topic><topic>自组装行为</topic><topic>透射电子显微镜</topic><topic>隔离结构</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Deng, Jin-ni</creatorcontrib><creatorcontrib>Wang, Wen-bin</creatorcontrib><creatorcontrib>Zheng, Zhao-hui</creatorcontrib><creatorcontrib>Ding, Xiao-bin</creatorcontrib><creatorcontrib>Peng, Yu-xing</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chinese journal of polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Deng, Jin-ni</au><au>Wang, Wen-bin</au><au>Zheng, Zhao-hui</au><au>Ding, Xiao-bin</au><au>Peng, Yu-xing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Self-assembly Behavior of Copolymers with Super Segregated Structure Containing Fluorinated Segments</atitle><jtitle>Chinese journal of polymer science</jtitle><stitle>Chin J Polym Sci</stitle><addtitle>Chinese Journal of Polymer Science</addtitle><date>2014-07-01</date><risdate>2014</risdate><volume>32</volume><issue>7</issue><spage>817</spage><epage>817</epage><pages>817-817</pages><issn>0256-7679</issn><eissn>1439-6203</eissn><abstract>Copolymers with super segregated structure of hydrophilic methoxy poly（ethylene glycol） （mPEG） and fluorophilic poly（1H,1H,2H,2H-perfluorodecyl acrylate） （PFA） were prepared. And just because of this super segregated structure which was resulted from the extremely strong incompatibility between the two blocks, several interesting self- assembly behaviors of the copolymers were displayed and studied under different conditions. Transmission electron microscope （TEM） showed that with the increase of PFA in the polymerization system, the incompatibility in this super segregated structure became stronger, and the self-assembly behavior changed from ball-like or rod-like to vesicles, and finally collapsed to sheet-like. The self-assembly behavior changed likewise when the initial concentration increased. And the interesting formation of these barrel-like and spindle-like vesicles was finally studied with different cooling speeds. It＇s finally found that with this super segregation structure, these new self-assembly morphology might be formed due to the extremely strong incompatibility between mPEG and PFA segments.</abstract><cop>Heidelberg</cop><pub>Chinese Chemical Society and Institute of Chemistry, CAS</pub><doi>10.1007/s10118-014-1476-z</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0256-7679 |
| ispartof | Chinese journal of polymer science, 2014-07, Vol.32 (7), p.817-817 |
| issn | 0256-7679 1439-6203 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1793260529 |
| source | SpringerNature Journals; Alma/SFX Local Collection |
| subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Copolymers Incompatibility Industrial Chemistry/Chemical Engineering MPEG MPEG encoders PFA Polymer Sciences Segments Self assembly Vesicles Video compression 不相容性 共聚物 氟化 种族 自组装行为 透射电子显微镜 隔离结构 |
| title | Self-assembly Behavior of Copolymers with Super Segregated Structure Containing Fluorinated Segments |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-12T18%3A02%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Self-assembly%20Behavior%20of%20Copolymers%20with%20Super%20Segregated%20Structure%20Containing%20Fluorinated%20Segments&rft.jtitle=Chinese%20journal%20of%20polymer%20science&rft.au=Deng,%20Jin-ni&rft.date=2014-07-01&rft.volume=32&rft.issue=7&rft.spage=817&rft.epage=817&rft.pages=817-817&rft.issn=0256-7679&rft.eissn=1439-6203&rft_id=info:doi/10.1007/s10118-014-1476-z&rft_dat=%3Cproquest_cross%3E1793260529%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1793260529&rft_id=info:pmid/&rft_cqvip_id=49825707&rfr_iscdi=true |