Green synthesis of the Cu/Fe3O4 nanoparticles using Morinda morindoides leaf aqueous extract: A highly efficient magnetically separable catalyst for the reduction of organic dyes in aqueous medium at room temperature
•Green synthesis of Cu/Fe3O4 nanoparticles by Morinda morindoides leaf extract.•Reduction of organic dyes in aqueous medium.•Catalyst was characterized using XRD, SEM, EDS, UV–visible, TEM, VSM and TGA-DTA.•The catalyst can be recovered by a magnet and reused several times without significant loss o...
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Veröffentlicht in: | Applied surface science 2016-02, Vol.364, p.636-644 |
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creator | Nasrollahzadeh, Mahmoud Atarod, Monireh Sajadi, S. Mohammad |
description | •Green synthesis of Cu/Fe3O4 nanoparticles by Morinda morindoides leaf extract.•Reduction of organic dyes in aqueous medium.•Catalyst was characterized using XRD, SEM, EDS, UV–visible, TEM, VSM and TGA-DTA.•The catalyst can be recovered by a magnet and reused several times without significant loss of catalytic activity.
This paper reports the green and in-situ preparation of the Cu/Fe3O4 magnetic nanocatalyst synthesized using Morinda morindoides leaf extract without stabilizers or surfactants. The catalyst was characterized by XRD, SEM, EDS, UV–visible, TEM, VSM and TGA-DTA. The catalytic performance of the resulting nanocatalyst was examined for the reduction of 4-nitrophenol (4-NP), Congo red (CR) and Rhodamine B (RhB) in an environmental friendly medium at room temperature. The catalyst was recovered using an external magnet and reused several times without appreciable loss of its catalytic activity. In addition, the stability of the recycled catalyst has been proved by SEM and EDS techniques. |
doi_str_mv | 10.1016/j.apsusc.2015.12.209 |
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This paper reports the green and in-situ preparation of the Cu/Fe3O4 magnetic nanocatalyst synthesized using Morinda morindoides leaf extract without stabilizers or surfactants. The catalyst was characterized by XRD, SEM, EDS, UV–visible, TEM, VSM and TGA-DTA. The catalytic performance of the resulting nanocatalyst was examined for the reduction of 4-nitrophenol (4-NP), Congo red (CR) and Rhodamine B (RhB) in an environmental friendly medium at room temperature. The catalyst was recovered using an external magnet and reused several times without appreciable loss of its catalytic activity. In addition, the stability of the recycled catalyst has been proved by SEM and EDS techniques.</description><identifier>ISSN: 0169-4332</identifier><identifier>EISSN: 1873-5584</identifier><identifier>DOI: 10.1016/j.apsusc.2015.12.209</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>CATALYSTS ; Catalytic properties ; Copper ; Cu/Fe3O4 ; DYES ; EXTRACTIVE METALLURGY ; FABRICATION ; IRON OXIDE ; Magnetic catalyst ; MICROSTRUCTURES ; Nanoparticles ; Nanostructure ; ORGANIC COMPOUNDS ; PARTICLES ; Recycled ; Reduction ; Synthesis</subject><ispartof>Applied surface science, 2016-02, Vol.364, p.636-644</ispartof><rights>2015 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c306t-901fecd5e46b5eb055c5225cc491c9747104b278831f1dc687f43a70e3c578fd3</citedby><cites>FETCH-LOGICAL-c306t-901fecd5e46b5eb055c5225cc491c9747104b278831f1dc687f43a70e3c578fd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.apsusc.2015.12.209$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids></links><search><creatorcontrib>Nasrollahzadeh, Mahmoud</creatorcontrib><creatorcontrib>Atarod, Monireh</creatorcontrib><creatorcontrib>Sajadi, S. Mohammad</creatorcontrib><title>Green synthesis of the Cu/Fe3O4 nanoparticles using Morinda morindoides leaf aqueous extract: A highly efficient magnetically separable catalyst for the reduction of organic dyes in aqueous medium at room temperature</title><title>Applied surface science</title><description>•Green synthesis of Cu/Fe3O4 nanoparticles by Morinda morindoides leaf extract.•Reduction of organic dyes in aqueous medium.•Catalyst was characterized using XRD, SEM, EDS, UV–visible, TEM, VSM and TGA-DTA.•The catalyst can be recovered by a magnet and reused several times without significant loss of catalytic activity.
This paper reports the green and in-situ preparation of the Cu/Fe3O4 magnetic nanocatalyst synthesized using Morinda morindoides leaf extract without stabilizers or surfactants. The catalyst was characterized by XRD, SEM, EDS, UV–visible, TEM, VSM and TGA-DTA. The catalytic performance of the resulting nanocatalyst was examined for the reduction of 4-nitrophenol (4-NP), Congo red (CR) and Rhodamine B (RhB) in an environmental friendly medium at room temperature. The catalyst was recovered using an external magnet and reused several times without appreciable loss of its catalytic activity. In addition, the stability of the recycled catalyst has been proved by SEM and EDS techniques.</description><subject>CATALYSTS</subject><subject>Catalytic properties</subject><subject>Copper</subject><subject>Cu/Fe3O4</subject><subject>DYES</subject><subject>EXTRACTIVE METALLURGY</subject><subject>FABRICATION</subject><subject>IRON OXIDE</subject><subject>Magnetic catalyst</subject><subject>MICROSTRUCTURES</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>ORGANIC COMPOUNDS</subject><subject>PARTICLES</subject><subject>Recycled</subject><subject>Reduction</subject><subject>Synthesis</subject><issn>0169-4332</issn><issn>1873-5584</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9UcFu1DAQjRBILIU_4DBHLtnasb1JOCBVK1qQWvUCZ8vrjHe9cuxgO4j8aT8Hp4s49vQsz5s3b-ZV1UdKtpTQ3fV5q6Y0J71tCBVb2hTsX1Ub2rWsFqLjr6tNofU1Z6x5W71L6UwIbUp1Uz3dRUQPafH5hMkmCAbKC_bz9S2yRw5e-TCpmK12mGBO1h_hIUTrBwXjMwY7lIpDZUD9mjHMCfBPjkrnz3ADJ3s8uQXQGKst-gyjOnoscsqV74RFWx0cglZZuSVlMCE-O4g4zDrb4FdLIR6VtxqGpYyy_v-gEQc7j6AyxBBGyDhOGFWeI76v3hjlEn74h1fVz9uvP_bf6vvHu-_7m_taM7LLdU-oQT0I5LuDwAMRQoumEVrznuq-5S0l_NC0XceooYPeda3hTLUEmRZtZwZ2VX266E4xFFMpy9Emjc4pvzqUtO1Zw8ut20LlF6qOIaWIRk7RjioukhK5BinP8hKkXIOUtCnYl7YvlzYsa_y2GGVaL6nL6hF1liWAlwX-AuXXrrM</recordid><startdate>20160228</startdate><enddate>20160228</enddate><creator>Nasrollahzadeh, Mahmoud</creator><creator>Atarod, Monireh</creator><creator>Sajadi, S. Mohammad</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160228</creationdate><title>Green synthesis of the Cu/Fe3O4 nanoparticles using Morinda morindoides leaf aqueous extract: A highly efficient magnetically separable catalyst for the reduction of organic dyes in aqueous medium at room temperature</title><author>Nasrollahzadeh, Mahmoud ; Atarod, Monireh ; Sajadi, S. Mohammad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c306t-901fecd5e46b5eb055c5225cc491c9747104b278831f1dc687f43a70e3c578fd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>CATALYSTS</topic><topic>Catalytic properties</topic><topic>Copper</topic><topic>Cu/Fe3O4</topic><topic>DYES</topic><topic>EXTRACTIVE METALLURGY</topic><topic>FABRICATION</topic><topic>IRON OXIDE</topic><topic>Magnetic catalyst</topic><topic>MICROSTRUCTURES</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>ORGANIC COMPOUNDS</topic><topic>PARTICLES</topic><topic>Recycled</topic><topic>Reduction</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nasrollahzadeh, Mahmoud</creatorcontrib><creatorcontrib>Atarod, Monireh</creatorcontrib><creatorcontrib>Sajadi, S. Mohammad</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied surface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nasrollahzadeh, Mahmoud</au><au>Atarod, Monireh</au><au>Sajadi, S. Mohammad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Green synthesis of the Cu/Fe3O4 nanoparticles using Morinda morindoides leaf aqueous extract: A highly efficient magnetically separable catalyst for the reduction of organic dyes in aqueous medium at room temperature</atitle><jtitle>Applied surface science</jtitle><date>2016-02-28</date><risdate>2016</risdate><volume>364</volume><spage>636</spage><epage>644</epage><pages>636-644</pages><issn>0169-4332</issn><eissn>1873-5584</eissn><abstract>•Green synthesis of Cu/Fe3O4 nanoparticles by Morinda morindoides leaf extract.•Reduction of organic dyes in aqueous medium.•Catalyst was characterized using XRD, SEM, EDS, UV–visible, TEM, VSM and TGA-DTA.•The catalyst can be recovered by a magnet and reused several times without significant loss of catalytic activity.
This paper reports the green and in-situ preparation of the Cu/Fe3O4 magnetic nanocatalyst synthesized using Morinda morindoides leaf extract without stabilizers or surfactants. The catalyst was characterized by XRD, SEM, EDS, UV–visible, TEM, VSM and TGA-DTA. The catalytic performance of the resulting nanocatalyst was examined for the reduction of 4-nitrophenol (4-NP), Congo red (CR) and Rhodamine B (RhB) in an environmental friendly medium at room temperature. The catalyst was recovered using an external magnet and reused several times without appreciable loss of its catalytic activity. In addition, the stability of the recycled catalyst has been proved by SEM and EDS techniques.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.apsusc.2015.12.209</doi><tpages>9</tpages></addata></record> |
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subjects | CATALYSTS Catalytic properties Copper Cu/Fe3O4 DYES EXTRACTIVE METALLURGY FABRICATION IRON OXIDE Magnetic catalyst MICROSTRUCTURES Nanoparticles Nanostructure ORGANIC COMPOUNDS PARTICLES Recycled Reduction Synthesis |
title | Green synthesis of the Cu/Fe3O4 nanoparticles using Morinda morindoides leaf aqueous extract: A highly efficient magnetically separable catalyst for the reduction of organic dyes in aqueous medium at room temperature |
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